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The pore effect on structure of molecular assemblies in the graphitic micropores was examined. The peak positions due to the first nearest neighbor CHCl3 in the electron radial distribution function of adsorbed phase agreed with those of bulk liquid, although their peak intensities were different. In narrow pores (pore width w = 1.1 nm), the peak intensities due to the first nearest molecule are stronger than the bulk liquid, because a peak due to the correlation between carbon walls and CHCl3 molecules was overlapped. In the wider pores of ACF W10 (w = 1.3 nm) having high CHCl3 removal efficiency from tap water, the intensity of the peak of r = 0.4 nm is the strongest. It suggests that CHCl3 molecules in the 1.3 nm micropores should be orientated for a Cl atom to meet with a carbon atom in wall surfaces. 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Structural study of CHCl3 molecular assemblies in micropores using X-ray techniques
http://hdl.handle.net/10091/183
http://hdl.handle.net/10091/183ece25feb-700f-496d-9c4f-0cf58d9cbb8a
名前 / ファイル | ライセンス | アクション |
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TCM molecular assembles.pdf (264.1 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2007-04-24 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Structural study of CHCl3 molecular assemblies in micropores using X-ray techniques | |||||
言語 | ||||||
言語 | eng | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1007/s10450-005-5917-4 | |||||
関連名称 | 10.1007/s10450-005-5917-4 | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Iiyama, T
× Iiyama, T× Kobayashi, Y× Matsumoto, A× Nakahigashi, Y× Ozeki, S |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Iiyama, T | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.uFnUOakh.html | |||||
信州大学研究者総覧へのリンク | ||||||
氏名 | Ozeki, S | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.WayVjVye.html | |||||
出版者 | ||||||
出版者 | SPRINGER | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY. 11: 169-172 (2005) | |||||
書誌情報 |
Adsorption : journal of the International Adsorption Society 巻 11, p. 169-172, 発行日 2005 |
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内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | The original publication is available at www.springerlink.com | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0929-5607 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA11074580 | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
WoS | ||||||
表示名 | Web of Science | |||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000232724900026 |