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During the melting and heat treatment, Ce4+ ions in the specimens were reduced to Ce3+ ions, and one or both of these ion species were then replaced with Li+ ions in the interlayers of the separated mica crystals. However, scanning transmission electron microscope (STEM) and Z-contrast imaging revealed that the mica crystals did not contain the same amount of Ce. On excitation at 254 nm, the parent glasses and glass-ceramics emitted blue light, which originated from the 5d to 4f transition of the Ce3+ ions. The emission of the glass-ceramic containing a smaller amount of Ce was attributed to the Ce3+ ions in both the glass phase and the mica crystals, whereas that of the glass-ceramics containing a larger amount of Ce was caused mainly by Ce3+ ions in the mica crystals. 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Microstructures and luminescent properties of Ce-doped transparent mica glass-ceramics
http://hdl.handle.net/10091/16077
http://hdl.handle.net/10091/16077a425581c-dbb0-41eb-89ab-bae832e45c65
名前 / ファイル | ライセンス | アクション |
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Microstructures_luminescent_properties_Ce-doped_transparent.pdf (1.2 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2012-11-21 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Microstructures and luminescent properties of Ce-doped transparent mica glass-ceramics | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | Cerium, Crystallization, Glass-ceramics, Mica, Luminescent properties | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Taruta, Seiichi
× Taruta, Seiichi× Iwasaki, Yoshitomo× Nishikiori, Hiromasa× Yamakami, Tomohiko× Yamaguchi, Tomohiro× Kitajima, Kunio× Okada, Kiyoshi |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Taruta, Seiichi | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.OacaZVkh.html | |||||
信州大学研究者総覧へのリンク | ||||||
氏名 | Nishikiori, Hiromasa | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.upkFbpkh.html | |||||
信州大学研究者総覧へのリンク | ||||||
氏名 | Yamaguchi, Tomohiro | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.WVnVbpkh.html | |||||
出版者 | ||||||
出版者 | ELSEVIER SCIENCE BV | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS. 177(7):504-509 (2012) | |||||
書誌情報 |
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS 巻 177, 号 7, p. 504-509, 発行日 2012-04-25 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Transparent mica glass-ceramics were prepared by heating parent glasses that had been doped with 0.5-15 mol% CeO2. During the melting and heat treatment, Ce4+ ions in the specimens were reduced to Ce3+ ions, and one or both of these ion species were then replaced with Li+ ions in the interlayers of the separated mica crystals. However, scanning transmission electron microscope (STEM) and Z-contrast imaging revealed that the mica crystals did not contain the same amount of Ce. On excitation at 254 nm, the parent glasses and glass-ceramics emitted blue light, which originated from the 5d to 4f transition of the Ce3+ ions. The emission of the glass-ceramic containing a smaller amount of Ce was attributed to the Ce3+ ions in both the glass phase and the mica crystals, whereas that of the glass-ceramics containing a larger amount of Ce was caused mainly by Ce3+ ions in the mica crystals. The dependence of the emission band of the parent glasses on the amount of Ce was a unique feature of the Ce-doped transparent mica glass-ceramics and was not observed in previous studies of Eu-doped parent glasses and mica glass-ceramics. | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0921-5107 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA10720431 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1016/j.mseb.2011.12.012 | |||||
関連名称 | 10.1016/j.mseb.2011.12.012 | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
WoS | ||||||
表示名 | Web of Science | |||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000303617000003 |