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メタクリル酸メチルの精密アニオン重合 -分子量,立体規則性,末端構造の三元同時制御-
http://hdl.handle.net/10091/00020195
http://hdl.handle.net/10091/0002019502c4baca-e3b5-461a-a49e-3be982c24064
名前 / ファイル | ライセンス | アクション |
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26620105_05.pdf (804.4 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2018-01-22 | |||||
タイトル | ||||||
言語 | ja | |||||
タイトル | メタクリル酸メチルの精密アニオン重合 -分子量,立体規則性,末端構造の三元同時制御- | |||||
言語 | ||||||
言語 | jpn | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.2324/gomu.88.80 | |||||
関連名称 | 10.2324/gomu.88.80 | |||||
キーワード | ||||||
主題 | Living Anionic Ploymerization, Stereoregularity, End-functionalization, Stereospecific Polymerization, Tacticity, Click Chemistry | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | Precise Anionic Polymerization of Methyl Methacrylate: Simultaneous Control of Molecular Weight, Stereoregularity, and End-Structure | |||||
著者 |
髙坂, 泰弘
× 髙坂, 泰弘× 北山, 辰樹 |
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信州大学研究者総覧へのリンク | ||||||
氏名 | 髙坂, 泰弘 | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.WNTUPVca.html | |||||
出版者 | ||||||
出版者 | 日本ゴム協会誌 | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 日本ゴム協会誌.88(3):80-85(2015) | |||||
書誌情報 |
日本ゴム協会誌 巻 88, 号 3, p. 80-85, 発行日 2015 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Stereospecific living anionic polymerizations of methyl methacrylate are described with the focus on precise control of polymer structures such as molecular weight and its dispersity, tacticity and end-groups. In particular, recently developed efficient termination reaction with α-(chloromethyl) acrylates is discussed, which affords stereoregular poly(methyl methacrylate)s possessing α,β-unsaturated esters at the ω-ends. The subsequent thiol-ene click reaction resulted in a quantitative end-functionalization. The terminating reaction is also useful to evaluate reactivity of monomers and stereospecificity of propagating species in the presence of some additives. | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0029-022X | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00189720 | |||||
他の資源との関係:URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://www.jstage.jst.go.jp/browse/gomu/-char/ja | |||||
関連名称 | https://www.jstage.jst.go.jp/browse/gomu/-char/ja | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |