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Synthesis and properties of novel bis(1,3-benzodithiolium)-type dications containing a biaryl unit: New redox systems undergoing reversible structural changes by electron transfer
http://hdl.handle.net/10091/1079
http://hdl.handle.net/10091/10795ebff030-ff76-4574-ab02-63256cb3230c
名前 / ファイル | ライセンス | アクション |
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Heterocycles_69_365_2006.pdf (643.7 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2008-06-05 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Synthesis and properties of novel bis(1,3-benzodithiolium)-type dications containing a biaryl unit: New redox systems undergoing reversible structural changes by electron transfer | |||||
言語 | ||||||
言語 | eng | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.3987/COM-06-S(O)45 | |||||
関連名称 | 10.3987/COM-06-S(O)45 | |||||
キーワード | ||||||
主題 | 1,3-benzodithiolium, biaryl, redox system, structural change, electrochemistry | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Ohta, A
× Ohta, A× Ueki, C× Uchiyama, Y× Fujimori, K |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Ohta, A | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.uaTeOUkh.html | |||||
出版者 | ||||||
出版者 | The Japan Institute of Heterocyclic Chemistry | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | HETEROCYCLES. 69(1): 365 (2006) | |||||
書誌情報 |
HETEROCYCLES 巻 69, 号 1, p. 365, 発行日 2006-12-01 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | In order to develop new redox systems which undergo reversible structural changes by electron transfer, bis(1,3-benzodithiolium)-type dications (5 21) containing a biaryl unit have been synthesized by hydride abstraction of the corresponding bis(1,3-benzodithiol-2-yl)biaryis (8). Reduction of 5 2, with zinc gave the corresponding intramolecular cyclization products (6), which reverted to 5(2+) by oxidation. Cyclic voltammetry also showed the efficient interconversion between both states. X-Ray analyses revealed that the twist angle of the biaryl unit decreases largely by reductive intramolecular cyclization. | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0385-5414 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00663739 | |||||
他の資源との関係:URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | http://www.heterocycles.jp/ | |||||
関連名称 | http://www.heterocycles.jp/ | |||||
権利 | ||||||
権利情報 | Copyright© 2006 The Japan Institute of Heterocyclic Chemistry | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
WoS | ||||||
表示名 | Web of Science | |||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000243651000034 |