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Reaction of spironaphthoxazine with acid
http://hdl.handle.net/10091/17209
http://hdl.handle.net/10091/172091e77cd3a-c133-4bc4-9ff7-eff6f9c82541
名前 / ファイル | ライセンス | アクション |
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Reaction_spironaphthoxazine_acid.pdf (999.0 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2013-10-21 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Reaction of spironaphthoxazine with acid | |||||
言語 | ||||||
言語 | eng | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1016/j.jphotochem.2012.11.004 | |||||
関連名称 | 10.1016/j.jphotochem.2012.11.004 | |||||
キーワード | ||||||
主題 | Spironaphthoxazine, Acid, Protonation, Complex, Fluorescence | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Nishikiori, Hiromasa
× Nishikiori, Hiromasa× Shimamura, Suguru× Fujii, Tsuneo |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Nishikiori, Hiromasa | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.upkFbpkh.html | |||||
出版者 | ||||||
出版者 | ELSEVIER SCIENCE SA | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY. 252:100-106 (2013) | |||||
書誌情報 |
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY 巻 252, p. 100-106, 発行日 2013-01-15 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The reaction of spironaphthoxazine (SNO) with acid in ethanol was investigated by spectroscopic analyses SNO was protonated and then transformed into a complex in an acidic ethanol solution in the dark. It is presumed that the complex contains a hydrated proton and its structure is similar to that of the metal complex of a merocyanine-type isomer photoderived from SNO based on its UV-vis absorption and fluorescence spectra. The complex dissociated into SNO by adding base. The complex was further changed under acidic conditions after a long time. Highly concentrated acid decomposed SNO to an indoline compound having a carboxyl group and 1-amino-2-naphthol, which was revealed by fluorescence, IR, and GC-MS analyses. These reaction processes were promoted by UV irradiation. | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1010-6030 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA10684407 | |||||
権利 | ||||||
権利情報 | Copyright© 2012 Elsevier B.V. | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
WoS | ||||||
表示名 | Web of Science | |||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000314480800014 |