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Matrix isolation studies of 185 nm light-induced cage reactions of o-chlorobenzaldehyde
http://hdl.handle.net/10091/17163
http://hdl.handle.net/10091/17163d266df22-ed95-4bb6-935e-58e47cbc721c
名前 / ファイル | ライセンス | アクション |
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Matrix_isolation_studies_185_nm_light-induced.pdf (619.4 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2013-09-18 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Matrix isolation studies of 185 nm light-induced cage reactions of o-chlorobenzaldehyde | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | o-Chlorobenzaldehyde, Benzoyl chloride, Photolysis, Cryogenic matrix | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Tanaka, Nobuaki
× Tanaka, Nobuaki× Fujiwara, Hiroki× Ogawa, Haruki× Nishikiori, Hiromasa |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Tanaka, Nobuaki | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.gpDFyhne.html | |||||
信州大学研究者総覧へのリンク | ||||||
氏名 | Nishikiori, Hiromasa | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.upkFbpkh.html | |||||
出版者 | ||||||
出版者 | ELSEVIER SCIENCE BV | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | JOURNAL OF MOLECULAR STRUCTURE. 1025:48-52 (2012) | |||||
書誌情報 |
JOURNAL OF MOLECULAR STRUCTURE 巻 1025, p. 48-52, 発行日 2012-10 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | VUV light photolysis of o-chlorobenzaldehyde (CBA) has been investigated by infrared spectroscopy in cryogenic Ar and O-2 matrices. Previously reported photoinduced rotational isomerization from anti- to syn-CBA was confirmed in the Ar matrix. In addition, absorption bands associated with photoinduced rearrangement to benzoyl chloride were observed accompanying the weak bands due to the CO photolysis product. However, in the reactive O-2 matrix, isomerization was observed and there was no evidence of benzoyl chloride formation. A kinetic analysis revealed that rearrangement was a minor process under the present excitation energy. The TD-B3LYP calculations show that as the excitation energy increases the predissociation channel will open and the repulsive (1)(pi, sigma(c-a)*) and 1(eta, sigma(c-a)*) states are directly achievable by the 185 nm excitation. Photoinduced rearrangement will be caused by the reaction of thus dissociated cage pairs. | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0022-2860 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00702852 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1016/j.molstruc.2012.04.054 | |||||
関連名称 | 10.1016/j.molstruc.2012.04.054 | |||||
権利 | ||||||
権利情報 | Copyright© 2012 Elsevier B.V. | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
WoS | ||||||
表示名 | Web of Science | |||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000309784100007 |