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The dye-doped nanocrystalline titania electrodes were prepared on the glass plates coated with ITO and normal crystalline titania films by the following two procedures: (1) the dye-doped titania gel films were prepared from a titanium alkoxide solution containing the dye and then steam-treated, and (2) the titanium alkoxide sol containing the dye was refluxed and then spread onto the plates. The photocurrent quantum efficiency remarkably increased by the steam treatment and the reflux compared to that of the untreated dye-doped electrode consisting of amorphous titania gel. The efficiency in the former was higher than that in the latter. The growth and crystallization of the titania particles and the decrease in the defect density by these treatments improved the electric conductivity. 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Photo-electric conversion in dye-doped nanocrystalline titania films
http://hdl.handle.net/10091/11119
http://hdl.handle.net/10091/11119c92699a0-ed6d-4459-9c69-49eabc737918
名前 / ファイル | ライセンス | アクション |
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Photo-electric_conversion_dye-doped_nanocrystalline.pdf (659.0 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2011-01-31 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Photo-electric conversion in dye-doped nanocrystalline titania films | |||||
言語 | ||||||
言語 | eng | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1016/j.jphotochem.2009.07.011 | |||||
関連名称 | 10.1016/j.jphotochem.2009.07.011 | |||||
キーワード | ||||||
主題 | Nanocrystal, Titania, Fluorescein, Photo-electric conversion, Sol-gel method | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Nishikiori, Hiromasa
× Nishikiori, Hiromasa× Uesugi, Yohei× Tanaka, Nobuaki× Fujii, Tsuneo |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Nishikiori, Hiromasa | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.upkFbpkh.html | |||||
信州大学研究者総覧へのリンク | ||||||
氏名 | Tanaka, Nobuaki | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.gpDFyhne.html | |||||
出版者 | ||||||
出版者 | ELSEVIER SCIENCE SA | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY. 207(2-3):204-208 (2009) | |||||
書誌情報 |
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY 巻 207, 号 2-3, p. 204-208, 発行日 2009-09-25 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Influences of the titania nanostructure and dye dispersion in a dye-doped titania electrode on its photoelectric conversion property were investigated by simple spectroscopic and electric measurements. The dye-doped nanocrystalline titania electrodes were prepared on the glass plates coated with ITO and normal crystalline titania films by the following two procedures: (1) the dye-doped titania gel films were prepared from a titanium alkoxide solution containing the dye and then steam-treated, and (2) the titanium alkoxide sol containing the dye was refluxed and then spread onto the plates. The photocurrent quantum efficiency remarkably increased by the steam treatment and the reflux compared to that of the untreated dye-doped electrode consisting of amorphous titania gel. The efficiency in the former was higher than that in the latter. The growth and crystallization of the titania particles and the decrease in the defect density by these treatments improved the electric conductivity. The steam treatment was the more prominent method because it enhanced the electric conductivity of the titania depending on its nanostructure and the dye-titania interaction depending on the dye dispersion. These factors appear to play important roles in transport in the electron through the electrode. | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1010-6030 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA10684407 | |||||
権利 | ||||||
権利情報 | Copyright (c) 2009 Elsevier B.V. | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
WoS | ||||||
表示名 | Web of Science | |||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000271351700008 |