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The lattice constant c decreased with a decrease in the layer charge while the lattice constants a and b increased. As the layer charge decreased, K-fluorine micas were changed into Na-fluorine micas more rapidly by NaB(C6H5)(4) treatment and were easier to cleave and change into the amorphous phase by grinding. The mica ceramics with lower layer charges showed lower electrical resistance than those with higher layer charges in the low-temperature region but higher electrical resistance in the high-temperature region. The results of the electrical resistance can be explained by the concentrations of the lattice vacancy and K+ ion in the interlayer. The dielectric loss tangent was influenced by the layer charge while the dielectric constant was almost unchanged. The chemical and physical properties of such micas are strongly dependent on the magnitude of the layer charge because the layer charge determines the interlayer bonding strength and the stability of mica structure. 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Effect of layer charge on chemical and physical properties of synthetic K-fluorine micas
http://hdl.handle.net/10091/150
http://hdl.handle.net/10091/150339baf71-c1f3-4272-af6a-fbeb90196c27
名前 / ファイル | ライセンス | アクション |
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J. Mater. Sci., 40, 21, 5597-5602 (2005)(S. Taruta).pdf (967.0 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2007-04-12 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Effect of layer charge on chemical and physical properties of synthetic K-fluorine micas | |||||
言語 | ||||||
言語 | eng | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1007/s10853-005-1428-7 | |||||
関連名称 | 10.1007/s10853-005-1428-7 | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Taruta, S
× Taruta, S× Obara, R× Takusagawa, N× Kitajima, K |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Taruta, S | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.OacaZVkh.html | |||||
出版者 | ||||||
出版者 | SPRINGER | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | JOURNAL OF MATERIALS SCIENCE. 40(21): 5597-5602 (2005) | |||||
書誌情報 |
JOURNAL OF MATERIALS SCIENCE 巻 40, 号 21, p. 5597-5602, 発行日 2005-11 |
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内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | The original publication is available at www.springerlink.com. | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0022-2461 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00701725 | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
WoS | ||||||
表示名 | Web of Science | |||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000232695400004 |