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Stereoregular poly (methyl methacrylate) with double-clickable ω-end: synthesis and click reaction
http://hdl.handle.net/10091/00020192
http://hdl.handle.net/10091/00020192b012d953-d517-4917-a1a9-e220b09d10f5
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||
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公開日 | 2018-01-22 | |||||||||||
タイトル | ||||||||||||
タイトル | Stereoregular poly (methyl methacrylate) with double-clickable ω-end: synthesis and click reaction | |||||||||||
言語 | ||||||||||||
言語 | eng | |||||||||||
DOI | ||||||||||||
関連識別子 | https://doi.org/10.1039/C5PY00357A | |||||||||||
関連名称 | 10.1039/C5PY00357A | |||||||||||
資源タイプ | ||||||||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
タイプ | journal article | |||||||||||
著者 |
Kohsaka, Yasuhiro
× Kohsaka, Yasuhiro
× Yamamoto, Kazuki
× Kitayama, Tatsuki
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信州大学研究者総覧へのリンク | ||||||||||||
氏名 | Kohsaka, Yasuhiro | |||||||||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.WNTUPVca.html | |||||||||||
出版者 | ||||||||||||
出版者 | The Royal Society of Chemistry | |||||||||||
引用 | ||||||||||||
内容記述 | Polymer Chemistry.6(19):3601-3607(2015) | |||||||||||
書誌情報 |
Polymer Chemistry 巻 6, 号 19, p. 3601-3607, 発行日 2015-05-21 |
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抄録 | ||||||||||||
内容記述 | Isotactic and syndiotactic poly(methyl methacrylate)s with orthogonally double-clickable terminal ends, that is, α,β-unsaturated esters for Michael addition-type thiol–ene reactions and azide or alkynyl groups for azide–alkyne click reactions, were prepared via a terminating reaction of stereospecific anionic polymerization with propargyl and 2-chloroethyl α-(chloromethyl)acrylates. The subsequent polymer modification via a double click reaction proceeded quantitatively in a one-pot system under ambient conditions. The facile and almost quantitative double-end-functionalization would open a new material design based on stereoregular PMMAs with controlled molecular weights. | |||||||||||
資源タイプ(コンテンツの種類) | ||||||||||||
ISSN | ||||||||||||
収録物識別子タイプ | ISSN | |||||||||||
収録物識別子 | 1759-9954 | |||||||||||
権利 | ||||||||||||
権利情報 | Polymer Chemistry.6(19):3601-3607(2015)- Reproduced by permission of The Royal Society of Chemistry. There shall be a link from this article to the PDF of the final published article on the RSC's website once this final version is available. | |||||||||||
出版タイプ | ||||||||||||
出版タイプ | AM | |||||||||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||
WoS | ||||||||||||
URL | http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000354198000005 |