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Systematic dynamic viscoelasticity measurements for chitin nanofibers prepared with various concentrations, disintegration times, acidities, and crystalline structures
Suenaga, Shin
Osada, Mitsumasa
© 2018. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
Chitin nanofiber
Dynamic viscoelasticity measurement
Scaling law
Epub 2018 Apr 16
Dynamic viscoelasticities were measured for chitin nanofiber (ChNF) dispersions prepared with various concentrations, disintegration times, acidities, and crystalline structures. The 0.05 w/v% dispersions of pH neutral ChNFs continuously exhibited elastic behavior. The 0.05 w/v% dispersions of acidified ChNFs, on the other hand, transitioned from a colloidal dispersion to a critical gel and then exhibited elastic behavior with increasing ChNF concentration. A double-logarithmic chart of the concentration vs. the storage modulus was prepared and indicated the fractal dimension and the nanostructure in the dispersion. The results determined that the neutral alpha- and beta-ChNFs were dispersed but showed some remaining aggregations and that the acidified beta-ChNFs were completely individualized. In addition, the alpha-chitin steadily disintegrated with increasing disintegration time, and the aspect ratio of the beta-chitin decreased as a result of the exscessive disintegration. The storage moduli of the ChNFs were greater than those of chitin solutions, nanorods, and nanowhiskers with the same solids concentrations.
Article
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES. 115:431-437 (2018)
ELSEVIER SCIENCE BV
2018-08
eng
journal article
AM
http://hdl.handle.net/10091/00020568
https://soar-ir.repo.nii.ac.jp/records/19807
http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search&DB=pubmed&term=29673956
29673956
https://doi.org/10.1016/j.ijbiomac.2018.04.082
10.1016/j.ijbiomac.2018.04.082
0141-8130
AA00233999
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
115
431
437
https://soar-ir.repo.nii.ac.jp/record/19807/files/Systematic_dynamic_viscoelasticity_measurements_chitin_nanofibers_prepared.pdf
application/pdf
792.3 kB
2019-04-16