2024-03-28T14:54:28Z
https://soar-ir.repo.nii.ac.jp/oai
oai:soar-ir.repo.nii.ac.jp:00013328
2022-12-14T04:27:50Z
1309:1310
Chemically-induced geometrical isomerization of stilbenes during peroxyoxalate chemiluminescence reaction: revisit to 'photochemistry without light'
Motoyoshiya, Jiro
Watanabe, Kanako
Takizawa, Airi
Shimizu, Hikaru
Maruyama, Takayuki
Peroxyoxalate chemiluminescence
Geometrical isomerization
Stilbene
Photochemistry without light
The chemically-induced isomerization of stilbenes during the peroxyoxalate chemiluminescence (PO-CL) reactions was reinvestigated. The PO-CL reactions using bis(2,4,6-trichlorophenyl) oxalate in the presence of several stilbenes (type A reaction) produced cis-stilbenes in 0-4% yields, which was dependent on the singlet excitation energy of the stilbenes. On the other hand, the PO-CL reactions of the oxalates, containing the stilbene moieties in the molecules (type B reaction), produced cis-stilbenes 0-9.3% yields, some of which were much more effective than the type A reactions considering the amount of the oxalate moiety as the energy supplier.
Article
TETRAHEDRON LETTERS. 55(3):619-622 (2014)
journal article
PERGAMON-ELSEVIER SCIENCE LTD
2014-01-15
application/pdf
TETRAHEDRON LETTERS
3
55
619
622
0040-4039
AA00861801
https://soar-ir.repo.nii.ac.jp/record/13328/files/Chemically-induced_geometrical_isomerization_stilbenes_during_peroxyoxalate.pdf
eng
10.1016/j.tetlet.2013.11.094
https://doi.org/10.1016/j.tetlet.2013.11.094
Copyright© 2013 Elsevier