2024-03-29T07:49:54Z
https://soar-ir.repo.nii.ac.jp/oai
oai:soar-ir.repo.nii.ac.jp:00014509
2022-12-14T04:05:05Z
1309:1314:1458:1461
テキスタイルの光電気化学的機能向上の研究
16-4-10 : 光伝導性液晶半導体の高速合成と自発配向試料の開発
太田, 和親
松瀬, 丈浩
木村, 睦
宇佐美, 久尚
It took extremely short reaction time only for 10min. to synthesize the long alkylthio-group-substituted metal-free compound, (C_8S)_8PcH_2(1), by the present microwave method giving significantly high yield(71 %), although it took very long reaction time for 20-24hrs to synthesize (C_8S)_8PcH_2(1), by the conventional oil bath method, It is noteworthy that this is the first example of syntheses of metal-free Pc derivatives in an organic solvent by microwave method. When the metal complexes. (C_8S)_8PcCu(2) and (C<_12>O)_8PcCu(6), were synthesized by microwave method, the optimal condition and the best yield depended very much on the kind of copper salts. Template effect of metal could not be seen in syntheses of the alkylthi0-group-substituted copper complex, (C_8S)_8PcCu(2), by microwave method. Oh the other hand, the template effect of metal could be seen in the cases of both (C_<12>O)_8PcCu(6) having alkoxy groups and the core complex PcCu. This difference may be attributed to difference of the intermediates. Further studies are necessary to clarify the hypothesis.
Article
先進ファイバー工学研究教育拠点研究成果報告書 11: 108-109(2005)
research report
信州大学繊維学部
2005-03-31
application/pdf
先進ファイバー工学研究教育拠点研究成果報告書
11
108
109
AA1200368X
https://soar-ir.repo.nii.ac.jp/record/14509/files/AFSTT11-410.pdf
jpn