2024-03-29T10:35:50Z
https://soar-ir.repo.nii.ac.jp/oai
oai:soar-ir.repo.nii.ac.jp:00019431
2022-12-14T04:27:28Z
1309:1310
Stereoregular poly (methyl methacrylate) with double-clickable ω-end: synthesis and click reaction
Kohsaka, Yasuhiro
Yamamoto, Kazuki
Kitayama, Tatsuki
Isotactic and syndiotactic poly(methyl methacrylate)s with orthogonally double-clickable terminal ends, that is, α,β-unsaturated esters for Michael addition-type thiol–ene reactions and azide or alkynyl groups for azide–alkyne click reactions, were prepared via a terminating reaction of stereospecific anionic polymerization with propargyl and 2-chloroethyl α-(chloromethyl)acrylates. The subsequent polymer modification via a double click reaction proceeded quantitatively in a one-pot system under ambient conditions. The facile and almost quantitative double-end-functionalization would open a new material design based on stereoregular PMMAs with controlled molecular weights.
Article
Polymer Chemistry.6(19):3601-3607(2015)
journal article
The Royal Society of Chemistry
2015-05-21
application/pdf
Polymer Chemistry
19
6
3601
3607
1759-9954
https://soar-ir.repo.nii.ac.jp/record/19431/files/26620105_01.pdf
eng
10.1039/C5PY00357A
https://doi.org/10.1039/C5PY00357A
Polymer Chemistry.6(19):3601-3607(2015)- Reproduced by permission of The Royal Society of Chemistry. There shall be a link from this article to the PDF of the final published article on the RSC's website once this final version is available.