{"created":"2021-03-01T06:13:06.556402+00:00","id":10231,"links":{},"metadata":{"_buckets":{"deposit":"128c9c97-cc7d-4d60-8261-bdb86a9ace28"},"_deposit":{"id":"10231","owners":[],"pid":{"revision_id":0,"type":"depid","value":"10231"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00010231","sets":["1016:1017"]},"author_link":["32272","32273","32274","32275","32276"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-10-28","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"43","bibliographicPageEnd":"8107","bibliographicPageStart":"8097","bibliographicVolumeNumber":"70","bibliographic_titles":[{"bibliographic_title":"TETRAHEDRON"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We developed a new one-pot reaction of phenolic acids to afford the corresponding esters and amides through acyl-protected and activated phenolic acid intermediates. The simultaneous protection/activation of phenolic acids with alkylchloroformates proceeded readily in the presence of DMAP at room temperature; subsequent addition of alcohols or amines afforded the corresponding esters or amides. The use of iso-butyloxycarbonyl as the protecting and activating group in the one-pot reactions afforded phenolic esters or amides in 91% average yield. As a practical example of this convenient synthesis, caffeic acid phenethyl ester (CAPE) was readily synthesized from commercially available caffeic acid and phenethyl alcohol in 95% yield, and an isotopomer of CAPE, [3,10-13C2]CAPE, was synthesized in 91% yield from [3-13C]caffeic acid and 2-[1-13C]phenethyl alcohol. This method may be useful for the convenient esterification and amidation of diverse phenolic acids.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"TETRAHEDRON. 70(43):8097-8107 (2014)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Nakamura, Kozo","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.upyCPUkh.html"},{"subitem_link_text":"Nakajima, Takero","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.ymTNuNkh.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000343344500037"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"PERGAMON-ELSEVIER SCIENCE LTD"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1016/j.tet.2014.08.028"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.tet.2014.08.028","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 2014 Elsevier Ltd. All rights reserved. NOTICE: this is the author's version of a work that was accepted for publication in TETRAHEDRON. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in TETRAHEDRON, VOL:70, ISSUE:43, (2014) DOI:10.1016/j.tet.2014.08.028"}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0040-4020","subitem_source_identifier_type":"PISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00861787","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Nakamura,  Kozo","creatorNameLang":"ja"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nakajima,  Takero","creatorNameLang":"ja"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Aoyama,  Toshifumi","creatorNameLang":"ja"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Okitsu,  Sho","creatorNameLang":"ja"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Koyama,  Masahiro","creatorNameLang":"ja"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2015-09-25"}],"displaytype":"detail","filename":"One-Pot_Esterification.pdf","filesize":[{"value":"797.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"One-Pot_Esterification.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/10231/files/One-Pot_Esterification.pdf"},"version_id":"d744b13b-2cbd-4752-aaa3-08ee86c45f64"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Esters","subitem_subject_scheme":"Other"},{"subitem_subject":"Amides","subitem_subject_scheme":"Other"},{"subitem_subject":"Phenolic acids","subitem_subject_scheme":"Other"},{"subitem_subject":"Caffeic acid phenethyl esters isotopomers","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"One-pot esterification and amidation of phenolic acids","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"One-pot esterification and amidation of phenolic acids","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1017"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2015-02-19"},"publish_date":"2015-02-19","publish_status":"0","recid":"10231","relation_version_is_last":true,"title":["One-pot esterification and amidation of phenolic acids"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:02:12.606697+00:00"}