{"created":"2021-03-01T06:13:06.796088+00:00","id":10235,"links":{},"metadata":{"_buckets":{"deposit":"b113ca39-9dc9-4816-8a20-f10c0c68b3f8"},"_deposit":{"id":"10235","owners":[],"pid":{"revision_id":0,"type":"depid","value":"10235"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00010235","sets":["1016:1017"]},"author_link":["32290","32291","32292","32293","32294","32295"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-07-23","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"30","bibliographicPageEnd":"4192","bibliographicPageStart":"4189","bibliographicVolumeNumber":"55","bibliographic_titles":[{"bibliographic_title":"TETRAHEDRON LETTERS"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Four diastereomers of tetradenolide, a cytotoxic α-pyrone isolated from Tetradenia riparia, were synthesized stereoselectively using the Z-selective Horner–Emmons reaction followed by acid catalyzed lactonization. Making comparison of the 1H and 13C NMR spectral data of the four diastereomers with those of the reported value of natural product did not lead to determine the relative stereochemistry of the natural tetradenolide. Thus detailed investigation of the spectral data of the related compounds led us to revise the structure of tetradenolide as deacetylboronolide.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"TETRAHEDRON LETTERS. 55(30):4189-4192 (2014)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Makabe, Hidefumi","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.jFSaPUkh.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000339128700040"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"PERGAMON-ELSEVIER SCIENCE LTD"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1016/j.tetlet.2014.05.109"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.tetlet.2014.05.109","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 2014 Elsevier Ltd. All rights reserved. /NOTICE: this is the author's version of a work that was accepted for publication in TETRAHEDRON LETTERS. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in TETRAHEDRON LETTERS, VOL:55, ISSUE:30, (2014) DOI:10.1016/j.tetlet.2014.05.109"}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0040-4039","subitem_source_identifier_type":"PISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00861801","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Tokuda,  Maki","creatorNameLang":"ja"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kurogome,  Yuji","creatorNameLang":"ja"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Katoh,  Rieko","creatorNameLang":"ja"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nohara,  Yukie","creatorNameLang":"ja"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hattori,  Yasunao","creatorNameLang":"ja"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Makabe,  Hidefumi","creatorNameLang":"ja"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2015-09-25"}],"displaytype":"detail","filename":"Synthesis_of_four_diastereomers.pdf","filesize":[{"value":"989.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Synthesis_of_four_diastereomers.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/10235/files/Synthesis_of_four_diastereomers.pdf"},"version_id":"c329872c-af7c-49b4-a848-d5a7bb5c2567"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Tetradenolide","subitem_subject_scheme":"Other"},{"subitem_subject":"alpha-Pyrone","subitem_subject_scheme":"Other"},{"subitem_subject":"Structural revision","subitem_subject_scheme":"Other"},{"subitem_subject":"Total synthesis","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis of four diastereomers and structural revision of tetradenolide","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis of four diastereomers and structural revision of tetradenolide","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1017"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2015-02-17"},"publish_date":"2015-02-17","publish_status":"0","recid":"10235","relation_version_is_last":true,"title":["Synthesis of four diastereomers and structural revision of tetradenolide"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:02:08.827790+00:00"}