@article{oai:soar-ir.repo.nii.ac.jp:00010740, author = {清水, 純夫 and 柴田, 久夫 and 唐澤, 伝英 and 森, 清明}, issue = {2}, journal = {信州大学農学部紀要}, month = {Dec}, note = {This paper was dealt with the structure elucidation of an unidentified diol obtained from the reduction product of rotundifolone ((+)-piperitenone oxdie 1) with lithium alminum hydride. This diol 5 was predominantly given after working up under acidic media, while under the alkaline condition two diols, trans and cis p-menth-4(8)-en-1, 3-diol (3 and 4) were obtained. The structure of compound 5 has been confirmed to be p-menth-3-en-1, 8-diol by chemical and spectrometric methods. The formation of 1, 8-diol 5 will proceed by the allylic rearrangement of 1, 3-dols (3 and 4)., Article, 信州大学農学部紀要 20(2): 219-225(1983)}, pages = {219--225}, title = {Rotundifoloneの水素化アルミニウムリチウム還元により得られる新モノテルペンダイオールの化学構造について}, volume = {20}, year = {1983} }