{"created":"2021-03-01T06:13:42.956163+00:00","id":10830,"links":{},"metadata":{"_buckets":{"deposit":"562dd6b8-728e-4232-bbd1-38b715c600d6"},"_deposit":{"id":"10830","owners":[],"pid":{"revision_id":0,"type":"depid","value":"10830"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00010830","sets":["1016:1018:1019:1060"]},"author_link":["34043","34044"],"item_10_alternative_title_1":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Tfp-アミノ酸からの新しい数種の2-テトラフロロエチル－シュードオキサゾロン－(5)の合成","subitem_alternative_title_language":"ja"}]},"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1974-06-25","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"92","bibliographicPageStart":"87","bibliographicVolumeNumber":"11","bibliographic_titles":[{"bibliographic_title":"信州大学農学部紀要"}]}]},"item_10_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"我々のグループでペプチド合成における新しいN-保護基を開発中であるが，その一環として既にTfp(テトラフロロプロピオニル)基の性質およびその応用を報告し，ラセミ化を伴う際の反応中間物であるシュードオキサゾロンを単離，同定した。今回，オキサゾロンにL-アミノ酸又はジペプチドを作用させる場合の不斉誘導因子を究明する目的で一連のオキキゾロンをTfp-アミノ酸から系統的に合成し，それらの構造決定を行なった。合成されたオキサゾロンは4位の置換基がメチル，エチル，n-プロピル，n-ブチル，イソブチル，ベンジルの各物質であり，それらはいずれもシュード型オキサゾロンであることを確認した。","subitem_description_language":"ja","subitem_description_type":"Abstract"}]},"item_10_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_10_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"信州大学農学部紀要 11(1): 87-92(1974)","subitem_description_type":"Other"}]},"item_10_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"信州大学農学部"}]},"item_10_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0583-0621","subitem_source_identifier_type":"ISSN"}]},"item_10_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00121352","subitem_source_identifier_type":"NCID"}]},"item_1627890569677":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"KAYAHARA,  Hiroshi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"TOMIDA,  Ichiro"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2015-09-25"}],"displaytype":"detail","filename":"Agriculture11-01-06.pdf","filesize":[{"value":"201.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Agriculture11-01-06.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/10830/files/Agriculture11-01-06.pdf"},"version_id":"3c441914-f853-4512-8ebc-51025c4db334"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis of Some New 2-Tetrafluoroethyl-pseudooxazolones-(5) from the Tfp-Amino Acids","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis of Some New 2-Tetrafluoroethyl-pseudooxazolones-(5) from the Tfp-Amino Acids","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["1060"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2009-03-03"},"publish_date":"2009-03-03","publish_status":"0","recid":"10830","relation_version_is_last":true,"title":["Synthesis of Some New 2-Tetrafluoroethyl-pseudooxazolones-(5) from the Tfp-Amino Acids"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-04T04:08:05.787874+00:00"}