{"created":"2021-03-01T06:13:44.289037+00:00","id":10852,"links":{},"metadata":{"_buckets":{"deposit":"39693853-71ef-4d1d-beea-6c4902c04341"},"_deposit":{"id":"10852","owners":[],"pid":{"revision_id":0,"type":"depid","value":"10852"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00010852","sets":["1016:1018:1019:1062"]},"author_link":["34086"],"item_10_alternative_title_1":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"水溶液中における金属ナトリウムによるモノテルペン,p-メンター1,3－ジエン-7-アールの還元機構の分子軌道法的研究","subitem_alternative_title_language":"ja"}]},"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1972-12-25","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"90","bibliographicPageStart":"83","bibliographicVolumeNumber":"9","bibliographic_titles":[{"bibliographic_title":"信州大学農学部紀要"}]}]},"item_10_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"水溶液中における金属ナトリウムによるテルペン類の還元法は、飽和、不飽和ケトンおよびアルデヒド類に広く適用でき、優れた立体選択性のあることを報告してきたが、還元機構は未だ確立されていない。今回、一つの試みとしてラジカル反応の指標によく用いられる自由原子価指数をHMO法で計算し、実験データとの比較から本還元がラジカル的に進行する裏付けとなる知見を得ることが出来た。","subitem_description_language":"ja","subitem_description_type":"Abstract"}]},"item_10_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_10_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"信州大学農学部紀要 9(2): 83-90(1972)","subitem_description_type":"Other"}]},"item_10_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"信州大学農学部"}]},"item_10_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0583-0621","subitem_source_identifier_type":"ISSN"}]},"item_10_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00121352","subitem_source_identifier_type":"NCID"}]},"item_1627890569677":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"KAYAHARA,  Hiroshi"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2015-09-25"}],"displaytype":"detail","filename":"Agriculture09-02-04.pdf","filesize":[{"value":"255.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Agriculture09-02-04.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/10852/files/Agriculture09-02-04.pdf"},"version_id":"4da1e47a-b77c-408e-b484-336524abc523"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"A Molecular Orbital Study of the Reduction Mechanism of Monoterpene, p-Mentha -1,3-dien-7-al, with Sodium in Aqueous Ammonia","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"A Molecular Orbital Study of the Reduction Mechanism of Monoterpene, p-Mentha -1,3-dien-7-al, with Sodium in Aqueous Ammonia","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["1062"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2009-03-03"},"publish_date":"2009-03-03","publish_status":"0","recid":"10852","relation_version_is_last":true,"title":["A Molecular Orbital Study of the Reduction Mechanism of Monoterpene, p-Mentha -1,3-dien-7-al, with Sodium in Aqueous Ammonia"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-04T04:07:49.649510+00:00"}