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  1. 040 理学部
  2. 0401 学術論文

Determination of the Standard Entropy Changes of Ion Transfer for 1-Alkylpyridinium Ions by Thermal Modulation Voltammetry with Laser Heating at a Water/1,2-Dichloroethane Interface

http://hdl.handle.net/10091/17859
1c0d452b-aeea-463c-ae77-2db9d9a90fb0
名前 / ファイル ライセンス アクション
Determination_Standard_Entropy_Changes_Ion_Transfer.pdf Determination_Standard_Entropy_Changes_Ion_Transfer.pdf (532.6 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2014-09-05
タイトル
言語 en
タイトル Determination of the Standard Entropy Changes of Ion Transfer for 1-Alkylpyridinium Ions by Thermal Modulation Voltammetry with Laser Heating at a Water/1,2-Dichloroethane Interface
言語
言語 eng
キーワード
主題Scheme Other
主題 Thermal modulation voltammetry
キーワード
主題Scheme Other
主題 laser heating
キーワード
主題Scheme Other
主題 water/1,2-dichloroethane interface
キーワード
主題Scheme Other
主題 standard entropy change
キーワード
主題Scheme Other
主題 ion transfer
キーワード
主題Scheme Other
主題 1-alkylpridinium ion
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Watanabe, Riho

× Watanabe, Riho

WEKO 35931

Watanabe, Riho

Search repository
Terauchi, Yui

× Terauchi, Yui

WEKO 35932

Terauchi, Yui

Search repository
Sakaue, Makoto

× Sakaue, Makoto

WEKO 35933

Sakaue, Makoto

Search repository
Hinoue, Teruo

× Hinoue, Teruo

WEKO 35934

Hinoue, Teruo

Search repository
信州大学研究者総覧へのリンク
氏名 Hinoue, Teruo
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.jmTajpnU.html
出版者
出版者 JAPAN SOC ANALYTICAL CHEMISTRY
引用
内容記述タイプ Other
内容記述 ANALYTICAL SCIENCES. 30(5):595-599 (2014)
書誌情報 ANALYTICAL SCIENCES

巻 30, 号 5, p. 595-599, 発行日 2014-05
抄録
内容記述タイプ Abstract
内容記述 When laser light impinges upon a liquid-liquid interface between an optically transparent aqueous and opaque organic phase from the aqueous to organic phase, the temperature at the interface and the interfacial region rises. Using this rise in temperature, we have proposed and developed thermal modulation voltammetry at an interface between two immiscible electrolyte solutions (TMV-ITIES) and have determined the standard entropy changes of ion transfer, Delta S-tr degrees'(O -> W). In this work, we have determined Delta S-tr degrees'(O -> W) for four 1-alkylpridinium ions, namely 1-methylpyridinium ion (MePy+), 1-ethylpyridinium ion (EtPy+), 1-propylpyridinium ion (PrPy+), and 1-buthylpyridinium ion (BuPy+) by TMV-ITIES. As a result, we obtained the Delta S-tr degrees'(O -> W) values of 108.0 +/- 0.5 (n = 3), 75.8 +/- 4.4, 55.6 +/- 1.2, and 42.7 +/- 0.9 J K-1 mol(-1) for MePy+, EtPy+, PrPy+, and BuPy+, respectively. From these values of Delta S-tr degrees'(O -> W), we have suggested that MePy+, EtPy+, and PrPy+ are classified as water structure-breaking ions and BuPy+ as a weak water structure-making ion. Further, we discuss the relationship between the standard free energy change, Delta G(tr)degrees'(O -> W), and Delta S-tr degrees'(O -> W) of ion transfer for 1-alkylpridinium ions and tetraalkylammonium ions.
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
ISSN
収録物識別子タイプ ISSN
収録物識別子 0910-6340
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA10500785
PubMed
関連識別子
識別子タイプ PMID
関連識別子 http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search&DB=pubmed&term=24813959
関連名称
関連名称 24813959
DOI
関連識別子
識別子タイプ DOI
関連識別子 https://doi.org/10.2116/analsci.30.595
関連名称
関連名称 10.2116/analsci.30.595
権利
権利情報 Copyright© 2014 The Japan Society for Analytical Chemistry
出版タイプ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
WoS
表示名 Web of Science
URL http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000336512600010
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