{"_buckets": {"deposit": "8f6d42ec-b669-4848-9471-b2568579f2c5"}, "_deposit": {"id": "11725", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "11725"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00011725", "sets": ["1169:1170"]}, "item_6_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2014-05", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "5", "bibliographicPageEnd": "599", "bibliographicPageStart": "595", "bibliographicVolumeNumber": "30", "bibliographic_titles": [{"bibliographic_title": "ANALYTICAL SCIENCES"}]}]}, "item_6_description_20": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "When laser light impinges upon a liquid-liquid interface between an optically transparent aqueous and opaque organic phase from the aqueous to organic phase, the temperature at the interface and the interfacial region rises. Using this rise in temperature, we have proposed and developed thermal modulation voltammetry at an interface between two immiscible electrolyte solutions (TMV-ITIES) and have determined the standard entropy changes of ion transfer, Delta S-tr degrees\u0027(O -\u003e W). In this work, we have determined Delta S-tr degrees\u0027(O -\u003e W) for four 1-alkylpridinium ions, namely 1-methylpyridinium ion (MePy+), 1-ethylpyridinium ion (EtPy+), 1-propylpyridinium ion (PrPy+), and 1-buthylpyridinium ion (BuPy+) by TMV-ITIES. As a result, we obtained the Delta S-tr degrees\u0027(O -\u003e W) values of 108.0 +/- 0.5 (n = 3), 75.8 +/- 4.4, 55.6 +/- 1.2, and 42.7 +/- 0.9 J K-1 mol(-1) for MePy+, EtPy+, PrPy+, and BuPy+, respectively. From these values of Delta S-tr degrees\u0027(O -\u003e W), we have suggested that MePy+, EtPy+, and PrPy+ are classified as water structure-breaking ions and BuPy+ as a weak water structure-making ion. Further, we discuss the relationship between the standard free energy change, Delta G(tr)degrees\u0027(O -\u003e W), and Delta S-tr degrees\u0027(O -\u003e W) of ion transfer for 1-alkylpridinium ions and tetraalkylammonium ions.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7\uff08\u30b3\u30f3\u30c6\u30f3\u30c4\u306e\u7a2e\u985e\uff09", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "\u5f15\u7528", "attribute_value_mlt": [{"subitem_description": "ANALYTICAL SCIENCES. 30(5):595-599 (2014)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "\u4fe1\u5dde\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7\u3078\u306e\u30ea\u30f3\u30af", "attribute_value_mlt": [{"subitem_link_text": "Hinoue, Teruo", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.jmTajpnU.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000336512600010"}]}, "item_6_publisher_4": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "JAPAN SOC ANALYTICAL CHEMISTRY"}]}, "item_6_relation_47": {"attribute_name": "PubMed", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "24813959"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search\u0026DB=pubmed\u0026term=24813959", "subitem_relation_type_select": "PMID"}}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.2116/analsci.30.595"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.2116/analsci.30.595", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "Copyright\u00a9 2014 The Japan Society for Analytical Chemistry"}]}, "item_6_select_64": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0910-6340", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0910-6340", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA10500785", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "Thermal modulation voltammetry; laser heating; water/1,2-dichloroethane interface; standard entropy change; ion transfer; 1-alkylpridinium ion"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "CONDUCTIVITY MEASUREMENTS; AQUEOUS-SOLUTIONS; MICROINTERFACE; ELECTROLYTE; ACETONE"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "When laser light impinges upon a liquid-liquid interface between an optically transparent aqueous and opaque organic phase from the aqueous to organic phase, the temperature at the interface and the interfacial region rises. Using this rise in temperature, we have proposed and developed thermal modulation voltammetry at an interface between two immiscible electrolyte solutions (TMV-ITIES) and have determined the standard entropy changes of ion transfer, Delta S-tr degrees\u0027(O -\u003e W). In this work, we have determined Delta S-tr degrees\u0027(O -\u003e W) for four 1-alkylpridinium ions, namely 1-methylpyridinium ion (MePy+), 1-ethylpyridinium ion (EtPy+), 1-propylpyridinium ion (PrPy+), and 1-buthylpyridinium ion (BuPy+) by TMV-ITIES. As a result, we obtained the Delta S-tr degrees\u0027(O -\u003e W) values of 108.0 +/- 0.5 (n = 3), 75.8 +/- 4.4, 55.6 +/- 1.2, and 42.7 +/- 0.9 J K-1 mol(-1) for MePy+, EtPy+, PrPy+, and BuPy+, respectively. From these values of Delta S-tr degrees\u0027(O -\u003e W), we have suggested that MePy+, EtPy+, and PrPy+ are classified as water structure-breaking ions and BuPy+ as a weak water structure-making ion. Further, we discuss the relationship between the standard free energy change, Delta G(tr)degrees\u0027(O -\u003e W), and Delta S-tr degrees\u0027(O -\u003e W) of ion transfer for 1-alkylpridinium ions and tetraalkylammonium ions."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Watanabe,  Riho"}], "nameIdentifiers": [{"nameIdentifier": "35931", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Terauchi,  Yui"}], "nameIdentifiers": [{"nameIdentifier": "35932", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sakaue,  Makoto"}], "nameIdentifiers": [{"nameIdentifier": "35933", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hinoue,  Teruo"}], "nameIdentifiers": [{"nameIdentifier": "35934", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Determination_Standard_Entropy_Changes_Ion_Transfer.pdf", "filesize": [{"value": "532.6 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 532600.0, "url": {"label": "Determination_Standard_Entropy_Changes_Ion_Transfer.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/11725/files/Determination_Standard_Entropy_Changes_Ion_Transfer.pdf"}, "version_id": "23b21c26-91e8-46d0-94e4-6499827010d7"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Thermal modulation voltammetry", "subitem_subject_scheme": "Other"}, {"subitem_subject": "laser heating", "subitem_subject_scheme": "Other"}, {"subitem_subject": "water/1,2-dichloroethane interface", "subitem_subject_scheme": "Other"}, {"subitem_subject": "standard entropy change", "subitem_subject_scheme": "Other"}, {"subitem_subject": "ion transfer", "subitem_subject_scheme": "Other"}, {"subitem_subject": "1-alkylpridinium ion", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Determination of the Standard Entropy Changes of Ion Transfer for 1-Alkylpyridinium Ions by Thermal Modulation Voltammetry with Laser Heating at a Water/1,2-Dichloroethane Interface", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Determination of the Standard Entropy Changes of Ion Transfer for 1-Alkylpyridinium Ions by Thermal Modulation Voltammetry with Laser Heating at a Water/1,2-Dichloroethane Interface"}]}, "item_type_id": "6", "owner": "1", "path": ["1169/1170"], "permalink_uri": "http://hdl.handle.net/10091/17859", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2014-09-05"}, "publish_date": "2014-09-05", "publish_status": "0", "recid": "11725", "relation": {}, "relation_version_is_last": true, "title": ["Determination of the Standard Entropy Changes of Ion Transfer for 1-Alkylpyridinium Ions by Thermal Modulation Voltammetry with Laser Heating at a Water/1,2-Dichloroethane Interface"], "weko_shared_id": null}