{"_buckets": {"deposit": "8f6d42ec-b669-4848-9471-b2568579f2c5"}, "_deposit": {"id": "11725", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "11725"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00011725", "sets": ["1170"]}, "author_link": ["35931", "35932", "35933", "35934"], "item_1628147817048": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_6_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2014-05", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "5", "bibliographicPageEnd": "599", "bibliographicPageStart": "595", "bibliographicVolumeNumber": "30", "bibliographic_titles": [{"bibliographic_title": "ANALYTICAL SCIENCES"}]}]}, "item_6_description_20": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "When laser light impinges upon a liquid-liquid interface between an optically transparent aqueous and opaque organic phase from the aqueous to organic phase, the temperature at the interface and the interfacial region rises. Using this rise in temperature, we have proposed and developed thermal modulation voltammetry at an interface between two immiscible electrolyte solutions (TMV-ITIES) and have determined the standard entropy changes of ion transfer, Delta S-tr degrees\u0027(O -\u003e W). In this work, we have determined Delta S-tr degrees\u0027(O -\u003e W) for four 1-alkylpridinium ions, namely 1-methylpyridinium ion (MePy+), 1-ethylpyridinium ion (EtPy+), 1-propylpyridinium ion (PrPy+), and 1-buthylpyridinium ion (BuPy+) by TMV-ITIES. As a result, we obtained the Delta S-tr degrees\u0027(O -\u003e W) values of 108.0 +/- 0.5 (n = 3), 75.8 +/- 4.4, 55.6 +/- 1.2, and 42.7 +/- 0.9 J K-1 mol(-1) for MePy+, EtPy+, PrPy+, and BuPy+, respectively. From these values of Delta S-tr degrees\u0027(O -\u003e W), we have suggested that MePy+, EtPy+, and PrPy+ are classified as water structure-breaking ions and BuPy+ as a weak water structure-making ion. Further, we discuss the relationship between the standard free energy change, Delta G(tr)degrees\u0027(O -\u003e W), and Delta S-tr degrees\u0027(O -\u003e W) of ion transfer for 1-alkylpridinium ions and tetraalkylammonium ions.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "資源タイプ（コンテンツの種類）", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "ANALYTICAL SCIENCES. 30(5):595-599 (2014)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "Hinoue, Teruo", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.jmTajpnU.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000336512600010"}]}, "item_6_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "JAPAN SOC ANALYTICAL CHEMISTRY"}]}, "item_6_relation_47": {"attribute_name": "PubMed", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "24813959"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?CMD=search\u0026DB=pubmed\u0026term=24813959", "subitem_relation_type_select": "PMID"}}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.2116/analsci.30.595"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.2116/analsci.30.595", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "Copyright© 2014 The Japan Society for Analytical Chemistry"}]}, "item_6_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0910-6340", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0910-6340", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA10500785", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "Thermal modulation voltammetry; laser heating; water/1,2-dichloroethane interface; standard entropy change; ion transfer; 1-alkylpridinium ion"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "CONDUCTIVITY MEASUREMENTS; AQUEOUS-SOLUTIONS; MICROINTERFACE; ELECTROLYTE; ACETONE"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "When laser light impinges upon a liquid-liquid interface between an optically transparent aqueous and opaque organic phase from the aqueous to organic phase, the temperature at the interface and the interfacial region rises. Using this rise in temperature, we have proposed and developed thermal modulation voltammetry at an interface between two immiscible electrolyte solutions (TMV-ITIES) and have determined the standard entropy changes of ion transfer, Delta S-tr degrees\u0027(O -\u003e W). In this work, we have determined Delta S-tr degrees\u0027(O -\u003e W) for four 1-alkylpridinium ions, namely 1-methylpyridinium ion (MePy+), 1-ethylpyridinium ion (EtPy+), 1-propylpyridinium ion (PrPy+), and 1-buthylpyridinium ion (BuPy+) by TMV-ITIES. As a result, we obtained the Delta S-tr degrees\u0027(O -\u003e W) values of 108.0 +/- 0.5 (n = 3), 75.8 +/- 4.4, 55.6 +/- 1.2, and 42.7 +/- 0.9 J K-1 mol(-1) for MePy+, EtPy+, PrPy+, and BuPy+, respectively. From these values of Delta S-tr degrees\u0027(O -\u003e W), we have suggested that MePy+, EtPy+, and PrPy+ are classified as water structure-breaking ions and BuPy+ as a weak water structure-making ion. Further, we discuss the relationship between the standard free energy change, Delta G(tr)degrees\u0027(O -\u003e W), and Delta S-tr degrees\u0027(O -\u003e W) of ion transfer for 1-alkylpridinium ions and tetraalkylammonium ions."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Watanabe,  Riho"}], "nameIdentifiers": [{"nameIdentifier": "35931", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Terauchi,  Yui"}], "nameIdentifiers": [{"nameIdentifier": "35932", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sakaue,  Makoto"}], "nameIdentifiers": [{"nameIdentifier": "35933", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hinoue,  Teruo"}], "nameIdentifiers": [{"nameIdentifier": "35934", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Determination_Standard_Entropy_Changes_Ion_Transfer.pdf", "filesize": [{"value": "532.6 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 532600.0, "url": {"label": "Determination_Standard_Entropy_Changes_Ion_Transfer.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/11725/files/Determination_Standard_Entropy_Changes_Ion_Transfer.pdf"}, "version_id": "23b21c26-91e8-46d0-94e4-6499827010d7"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "Thermal modulation voltammetry", "subitem_subject_scheme": "Other"}, {"subitem_subject": "laser heating", "subitem_subject_scheme": "Other"}, {"subitem_subject": "water/1,2-dichloroethane interface", "subitem_subject_scheme": "Other"}, {"subitem_subject": "standard entropy change", "subitem_subject_scheme": "Other"}, {"subitem_subject": "ion transfer", "subitem_subject_scheme": "Other"}, {"subitem_subject": "1-alkylpridinium ion", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Determination of the Standard Entropy Changes of Ion Transfer for 1-Alkylpyridinium Ions by Thermal Modulation Voltammetry with Laser Heating at a Water/1,2-Dichloroethane Interface", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Determination of the Standard Entropy Changes of Ion Transfer for 1-Alkylpyridinium Ions by Thermal Modulation Voltammetry with Laser Heating at a Water/1,2-Dichloroethane Interface", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1170"], "permalink_uri": "http://hdl.handle.net/10091/17859", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2014-09-05"}, "publish_date": "2014-09-05", "publish_status": "0", "recid": "11725", "relation": {}, "relation_version_is_last": true, "title": ["Determination of the Standard Entropy Changes of Ion Transfer for 1-Alkylpyridinium Ions by Thermal Modulation Voltammetry with Laser Heating at a Water/1,2-Dichloroethane Interface"], "weko_shared_id": -1}