{"created":"2021-03-01T06:14:37.510672+00:00","id":11727,"links":{},"metadata":{"_buckets":{"deposit":"cfe6d1f9-46f0-4e95-aca9-cc1264f39985"},"_deposit":{"id":"11727","owners":[],"pid":{"revision_id":0,"type":"depid","value":"11727"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00011727","sets":["1169:1170"]},"author_link":["35937","35938","35939","35940","35941","35942"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"1547","bibliographicPageStart":"1541","bibliographicVolumeNumber":"86","bibliographic_titles":[{"bibliographic_title":"HETEROCYCLES"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"8H-7,9-Bis(methoxycarbonyl)-5,11-methano[11]anuleno[c]furan-8-one (3) undergoes [4+3] cycloaddition with an oxyallyl species generated from 2,4-dibromo-3-pentanone in the presence of KI and copper, followed by dehydration in fluorosulfuric acid to give cyclohepta[11]annulenedione diester 9. After hydrolysis of the ester groups, decarboxylation yielded the title quinone 6. The H-1 NMR spectrum of 6 in D2SO4 indicates generation of its protonated dicationic species.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"HETEROCYCLES. 86(2):1541-1547 (2012)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Oda, Mitsunori","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.gNAmbVkm.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000314390600056"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"PERGAMON-ELSEVIER SCIENCE LTD"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.3987/COM-12-S(N)75"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.3987/COM-12-S(N)75","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright© 2013 The Japan Institute of Heterocyclic Chemistry"}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0385-5414","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00663739","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kuroda,  Shigeyasu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Matsumoto,  Naoko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Zhang,  Yanmei"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Miyatake,  Ryuta"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fujiwara,  Yurie"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Oda,  Mitsunori"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2015-09-28"}],"displaytype":"detail","filename":"COM-12-S(N)75.pdf","filesize":[{"value":"518.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"COM-12-S(N)75.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/11727/files/COM-12-S(N)75.pdf"},"version_id":"46f9eedb-2f9b-4277-a7e9-c1090aa21b24"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Methano[11]annulene","subitem_subject_scheme":"Other"},{"subitem_subject":"Furan","subitem_subject_scheme":"Other"},{"subitem_subject":"Dicationic Species","subitem_subject_scheme":"Other"},{"subitem_subject":"[4+3] Cycloaddition","subitem_subject_scheme":"Other"},{"subitem_subject":"Protonation","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis of a Novel Non-Benzenoid Quinone, 3,10-Dihydro-2,4-dimethyl-7,13-methanocyclohepta[11]annulene-3,10-dione, from 8H-7,9-Bis(methoxycarbonyl)-5,11-methano[11]annuleno[c]furan-8-one","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis of a Novel Non-Benzenoid Quinone, 3,10-Dihydro-2,4-dimethyl-7,13-methanocyclohepta[11]annulene-3,10-dione, from 8H-7,9-Bis(methoxycarbonyl)-5,11-methano[11]annuleno[c]furan-8-one","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1170"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2013-12-04"},"publish_date":"2013-12-04","publish_status":"0","recid":"11727","relation_version_is_last":true,"title":["Synthesis of a Novel Non-Benzenoid Quinone, 3,10-Dihydro-2,4-dimethyl-7,13-methanocyclohepta[11]annulene-3,10-dione, from 8H-7,9-Bis(methoxycarbonyl)-5,11-methano[11]annuleno[c]furan-8-one"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:11:19.199041+00:00"}