{"_buckets": {"deposit": "08b76dcc-214e-4c22-8e5b-0bcd7deccb70"}, "_deposit": {"id": "11825", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "11825"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00011825", "sets": ["1170"]}, "author_link": ["36219", "36220", "36221", "36222", "36223"], "item_1628147817048": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_6_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2010-09-29", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "39", "bibliographicPageEnd": "5130", "bibliographicPageStart": "5127", "bibliographicVolumeNumber": "51", "bibliographic_titles": [{"bibliographic_title": "TETRAHEDRON LETTERS"}]}]}, "item_6_description_20": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Azulene derivatives reacted with N-oxide of several heterocycles in the presence of trifluoromethanesultonic anhydride (Tf(2)O) to afford 1-(pyridyl, quinolyl, and isoquinolyl)azulenes in good yield, respectively. In the case of the reaction with the 1-azulenyl methyl sulfide (12), 1,1\u0027-biazulene derivative 13 was obtained under the similar reaction conditions. The first synthesis of unsymmetrical 1,3-di(pyridyl)azulene derivative was also established via our new preparation method following the electrophilic pyriclinylation using the reaction with pyridine in the presence of Tf(2)O.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "資源タイプ（コンテンツの種類）", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "TETRAHEDRON LETTERS. 51(39):5127-5130 (2010)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "Shoji, Taku", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000282150800008"}]}, "item_6_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "PERGAMON-ELSEVIER SCIENCE LTD"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1016/j.tetlet.2010.07.090"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1016/j.tetlet.2010.07.090", "subitem_relation_type_select": "DOI"}}]}, "item_6_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0040-4039", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0040-4039", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00861801", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "Azulene; Heterocycle; Electrophilic arylation"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "CROSS-COUPLING REACTION; TERTIARY AMINE OXIDES; AROMATIC N-OXIDES; CATALYZED DIRECT ARYLATION; HOLE-INJECTING MATERIAL; 1ST ORGANOTIN REAGENTS; SITE-SELECTIVE SP(2); REDOX BEHAVIOR; ACYLATING AGENTS; EASY ACCESS"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "Azulene derivatives reacted with N-oxide of several heterocycles in the presence of trifluoromethanesultonic anhydride (Tf(2)O) to afford 1-(pyridyl, quinolyl, and isoquinolyl)azulenes in good yield, respectively. In the case of the reaction with the 1-azulenyl methyl sulfide (12), 1,1\u0027-biazulene derivative 13 was obtained under the similar reaction conditions. The first synthesis of unsymmetrical 1,3-di(pyridyl)azulene derivative was also established via our new preparation method following the electrophilic pyriclinylation using the reaction with pyridine in the presence of Tf(2)O. (c) 2010 Elsevier Ltd. All rights reserved."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Shoji,  Taku"}], "nameIdentifiers": [{"nameIdentifier": "36219", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okada,  Kazuyuki"}], "nameIdentifiers": [{"nameIdentifier": "36220", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ito,  Shunji"}], "nameIdentifiers": [{"nameIdentifier": "36221", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Toyota,  Kozo"}], "nameIdentifiers": [{"nameIdentifier": "36222", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Morita,  Noboru"}], "nameIdentifiers": [{"nameIdentifier": "36223", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Tetrahedron Letters 51 (2010) 5127.pdf", "filesize": [{"value": "226.5 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 226500.0, "url": {"label": "Tetrahedron Letters 51 (2010) 5127.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/11825/files/Tetrahedron Letters 51 (2010) 5127.pdf"}, "version_id": "7ac437f8-ecb6-43ec-9869-8638c56062e1"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "Azulene", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Heterocycle", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Electrophilic arylation", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis of 1-(pyridyl, quinolyl, and isoquinolyl)azulenes by Reissert-Henze type reaction", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Synthesis of 1-(pyridyl, quinolyl, and isoquinolyl)azulenes by Reissert-Henze type reaction", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1170"], "permalink_uri": "http://hdl.handle.net/10091/16093", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2012-11-26"}, "publish_date": "2012-11-26", "publish_status": "0", "recid": "11825", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis of 1-(pyridyl, quinolyl, and isoquinolyl)azulenes by Reissert-Henze type reaction"], "weko_shared_id": -1}