{"_buckets": {"deposit": "08b76dcc-214e-4c22-8e5b-0bcd7deccb70"}, "_deposit": {"id": "11825", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "11825"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00011825"}, "item_6_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2010-09-29", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "39", "bibliographicPageEnd": "5130", "bibliographicPageStart": "5127", "bibliographicVolumeNumber": "51", "bibliographic_titles": [{"bibliographic_title": "TETRAHEDRON LETTERS"}]}]}, "item_6_description_20": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Azulene derivatives reacted with N-oxide of several heterocycles in the presence of trifluoromethanesultonic anhydride (Tf(2)O) to afford 1-(pyridyl, quinolyl, and isoquinolyl)azulenes in good yield, respectively. In the case of the reaction with the 1-azulenyl methyl sulfide (12), 1,1\u0027-biazulene derivative 13 was obtained under the similar reaction conditions. The first synthesis of unsymmetrical 1,3-di(pyridyl)azulene derivative was also established via our new preparation method following the electrophilic pyriclinylation using the reaction with pyridine in the presence of Tf(2)O.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7\uff08\u30b3\u30f3\u30c6\u30f3\u30c4\u306e\u7a2e\u985e\uff09", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "\u5f15\u7528", "attribute_value_mlt": [{"subitem_description": "TETRAHEDRON LETTERS. 51(39):5127-5130 (2010)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "\u4fe1\u5dde\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7\u3078\u306e\u30ea\u30f3\u30af", "attribute_value_mlt": [{"subitem_link_text": "Shoji, Taku", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.gmShOakh.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000282150800008"}]}, "item_6_publisher_4": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "PERGAMON-ELSEVIER SCIENCE LTD"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1016/j.tetlet.2010.07.090"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.1016/j.tetlet.2010.07.090", "subitem_relation_type_select": "DOI"}}]}, "item_6_select_64": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0040-4039", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0040-4039", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00861801", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "Azulene; Heterocycle; Electrophilic arylation"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "CROSS-COUPLING REACTION; TERTIARY AMINE OXIDES; AROMATIC N-OXIDES; CATALYZED DIRECT ARYLATION; HOLE-INJECTING MATERIAL; 1ST ORGANOTIN REAGENTS; SITE-SELECTIVE SP(2); REDOX BEHAVIOR; ACYLATING AGENTS; EASY ACCESS"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "Azulene derivatives reacted with N-oxide of several heterocycles in the presence of trifluoromethanesultonic anhydride (Tf(2)O) to afford 1-(pyridyl, quinolyl, and isoquinolyl)azulenes in good yield, respectively. In the case of the reaction with the 1-azulenyl methyl sulfide (12), 1,1\u0027-biazulene derivative 13 was obtained under the similar reaction conditions. The first synthesis of unsymmetrical 1,3-di(pyridyl)azulene derivative was also established via our new preparation method following the electrophilic pyriclinylation using the reaction with pyridine in the presence of Tf(2)O. (c) 2010 Elsevier Ltd. All rights reserved."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Shoji,  Taku"}], "nameIdentifiers": [{"nameIdentifier": "36219", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okada,  Kazuyuki"}], "nameIdentifiers": [{"nameIdentifier": "36220", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ito,  Shunji"}], "nameIdentifiers": [{"nameIdentifier": "36221", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Toyota,  Kozo"}], "nameIdentifiers": [{"nameIdentifier": "36222", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Morita,  Noboru"}], "nameIdentifiers": [{"nameIdentifier": "36223", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Tetrahedron Letters 51 (2010) 5127.pdf", "filesize": [{"value": "226.5 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 226500.0, "url": {"label": "Tetrahedron Letters 51 (2010) 5127.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/11825/files/Tetrahedron Letters 51 (2010) 5127.pdf"}, "version_id": "7ac437f8-ecb6-43ec-9869-8638c56062e1"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Azulene", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Heterocycle", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Electrophilic arylation", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis of 1-(pyridyl, quinolyl, and isoquinolyl)azulenes by Reissert-Henze type reaction", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Synthesis of 1-(pyridyl, quinolyl, and isoquinolyl)azulenes by Reissert-Henze type reaction"}]}, "item_type_id": "6", "owner": "1", "path": ["1169/1170"], "permalink_uri": "http://hdl.handle.net/10091/16093", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2012-11-26"}, "publish_date": "2012-11-26", "publish_status": "0", "recid": "11825", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis of 1-(pyridyl, quinolyl, and isoquinolyl)azulenes by Reissert-Henze type reaction"], "weko_shared_id": null}