{"created":"2021-03-01T06:14:47.297471+00:00","id":11885,"links":{},"metadata":{"_buckets":{"deposit":"a59597f2-0527-45af-a1f3-6e9b651c576d"},"_deposit":{"id":"11885","owners":[],"pid":{"revision_id":0,"type":"depid","value":"11885"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00011885","sets":["1169:1170"]},"author_link":["36410","36411","36412","36413"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-08-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"20","bibliographicPageEnd":"5537","bibliographicPageStart":"5532","bibliographicVolumeNumber":"55","bibliographic_titles":[{"bibliographic_title":"Electrochimica Acta"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Glyphosate, a phosphorus-containing amino acid type herbicide was used as a coreactant for studying of electrochemiluminescence (ECL) reaction of tris(2,2'-bipyridyl)ruthenium(II) [Ru(bpy)(3)(2+)] in an aqueous solution. In a phosphate buffer solution of pH 8, glyphosate itself was known to be electrochemically inactive at glassy carbon electrode, however, it participated in a homogeneous chemical reaction with the electrogenerated Ru(bpy)(3)(3+), and resulted in producing Ru(bpy)(3)(2+) species at the electrode surface. Kinetic and mechanistic information for the catalysis of glyphosate oxidation were evaluated by the steady-state voltammetric measurement with an ultramicroelectrode. The simulated cyclic voltammogram based on this mechanism was in good agreement with that obtained experimentally. ECL reaction of Ru(bpy)(3)(2+)/glyphosate system was found to be strongly dependent on the media pH. In a pH region of 5-9, an ECL wave appeared at ca. +1.1 V vs. Ag/AgCl, which was caused by the generation of *Ru(bpy)(3)(2+) via a Ru(bpy)(3)(3+)-mediated oxidation of glyphosate. When pH >10, a second ECL wave was observed at ca. +1.35 V vs. Ag/AgCl, which was believed to be associated with a reaction between Ru(bpy)(3)(3+) and the species from direct oxidation of GLYP at a GC electrode surface.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Electrochimica Acta 55(20):5532-5537 (2010)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Jin, Jiye","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.jUThymkV.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000280422800002"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"PERGAMON-ELSEVIER SCIENCE LTD"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1016/j.electacta.2010.04.031"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.electacta.2010.04.031","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2010 Elsevier Ltd."}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00134686","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00633261","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Jin,  Jiye"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Takahashi,  Fumiki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kaneko,  Tsutomu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nakamura,  Toshio"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2015-09-28"}],"displaytype":"detail","filename":"Characterization_electrochemiluminescence.pdf","filesize":[{"value":"566.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Characterization_electrochemiluminescence.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/11885/files/Characterization_electrochemiluminescence.pdf"},"version_id":"cb6373c0-ad0d-49db-bc40-648c72dbf19d"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Electrogenerated chemiluminescence of Ru(bpy)(3)(2+)","subitem_subject_scheme":"Other"},{"subitem_subject":"Glyphosate","subitem_subject_scheme":"Other"},{"subitem_subject":"EC' catalytic reaction","subitem_subject_scheme":"Other"},{"subitem_subject":"Ultramicroelectrode","subitem_subject_scheme":"Other"},{"subitem_subject":"Potential modulated ECL","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Characterization of electrochemiluminescence of tris(2,2′-bipyridine)ruthenium(II) with glyphosate as coreactant in aqueous solution","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Characterization of electrochemiluminescence of tris(2,2′-bipyridine)ruthenium(II) with glyphosate as coreactant in aqueous solution","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1170"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2010-10-22"},"publish_date":"2010-10-22","publish_status":"0","recid":"11885","relation_version_is_last":true,"title":["Characterization of electrochemiluminescence of tris(2,2′-bipyridine)ruthenium(II) with glyphosate as coreactant in aqueous solution"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:38:23.565308+00:00"}