{"_buckets": {"deposit": "8f3648f8-9adc-49c4-98fa-35674b44a797"}, "_deposit": {"id": "11922", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "11922"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00011922", "sets": ["1170"]}, "author_link": ["36527", "36528", "36529", "36530"], "item_1628147817048": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_6_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2008-12-01", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "49", "bibliographicPageEnd": "7061", "bibliographicPageStart": "7058", "bibliographicVolumeNumber": "49", "bibliographic_titles": [{"bibliographic_title": "TETRAHEDRON LETTERS"}]}]}, "item_6_description_30": {"attribute_name": "資源タイプ（コンテンツの種類）", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_31": {"attribute_name": "フォーマット：mimeタイプ", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "TETRAHEDRON LETTERS. 49(49): 7058-7061 (2008)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "Oda, M", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.gNAmbVkm.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000260843700032"}]}, "item_6_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "PERGAMON-ELSEVIER SCIENCE LTD"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1016/j.tetlet.2008.09.142"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1016/j.tetlet.2008.09.142", "subitem_relation_type_select": "DOI"}}]}, "item_6_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0040-4039", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0040-4039", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00861801", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "1,2-3,4-5,6-TRIS(BICYCLO\u003c2.2.2\u003eOCTENO)TROPYLIUM ION; LAYERED COMPOUNDS; TROPYLIUM CATION; STABILITY; TETRAFLUOROBORATE; SPIROCONJUGATION; RING; SUPERPHANE; TRANSITION"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "Spiro[1H-azulenium-1,9\u0027-fluorene] (3) perchlorate was synthesized in five steps starting from fluorenone and trimethylsilyl enol ether of 1-acetylcycloheptatriene. The pK(R)+ value of 3 was determined to be 7.8. A characteristic absorption band of 3 in acetonitrile was observed at 430 nm, which shows a bathochromic shift in dichloromethane, indicating the first example of the intramolecular charge-transfer interaction between orthogonally arranged units of an azulenium ion having a tropylium ion ring and fluorene having two benzene rings. (c) 2008 Elsevier Ltd. All rights reserved."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Oda,  M"}], "nameIdentifiers": [{"nameIdentifier": "36527", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nakajima,  N"}], "nameIdentifiers": [{"nameIdentifier": "36528", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Thanh,  NC"}], "nameIdentifiers": [{"nameIdentifier": "36529", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kuroda,  S"}], "nameIdentifiers": [{"nameIdentifier": "36530", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "TL_text_oda.pdf", "filesize": [{"value": "169.8 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 169800.0, "url": {"label": "TL_text_oda.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/11922/files/TL_text_oda.pdf"}, "version_id": "ff349511-e3d6-4ea6-be87-6c666b8d7aef"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Spiro[1H-azulenium-1,9 \u0027-fluorene] perchlorate. Intramolecular charge-transfer interaction between orthogonally arranged units of the azulenium cation and fluorene", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Spiro[1H-azulenium-1,9 \u0027-fluorene] perchlorate. Intramolecular charge-transfer interaction between orthogonally arranged units of the azulenium cation and fluorene", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1170"], "permalink_uri": "http://hdl.handle.net/10091/3071", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2009-05-19"}, "publish_date": "2009-05-19", "publish_status": "0", "recid": "11922", "relation": {}, "relation_version_is_last": true, "title": ["Spiro[1H-azulenium-1,9 \u0027-fluorene] perchlorate. Intramolecular charge-transfer interaction between orthogonally arranged units of the azulenium cation and fluorene"], "weko_shared_id": -1}