{"created":"2021-03-01T06:14:52.393224+00:00","id":11969,"links":{},"metadata":{"_buckets":{"deposit":"cabb5085-ab59-4469-8502-47f2560f4d00"},"_deposit":{"id":"11969","owners":[],"pid":{"revision_id":0,"type":"depid","value":"11969"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00011969","sets":["1169:1170"]},"author_link":["36682","36683","36684","36685"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2006-12-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageStart":"365","bibliographicVolumeNumber":"69","bibliographic_titles":[{"bibliographic_title":"HETEROCYCLES"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"In order to develop new redox systems which undergo reversible structural changes by electron transfer, bis(1,3-benzodithiolium)-type dications (5 21) containing a biaryl unit have been synthesized by hydride abstraction of the corresponding bis(1,3-benzodithiol-2-yl)biaryis (8). Reduction of 5 2, with zinc gave the corresponding intramolecular cyclization products (6), which reverted to 5(2+) by oxidation. Cyclic voltammetry also showed the efficient interconversion between both states. X-Ray analyses revealed that the twist angle of the biaryl unit decreases largely by reductive intramolecular cyclization.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"HETEROCYCLES. 69(1): 365 (2006)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Ohta, A","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.uaTeOUkh.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000243651000034"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Japan Institute of Heterocyclic Chemistry"}]},"item_6_relation_46":{"attribute_name":"他の資源との関係：URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://www.heterocycles.jp/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.heterocycles.jp/","subitem_relation_type_select":"URI"}}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.3987/COM-06-S(O)45"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.3987/COM-06-S(O)45","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright© 2006 The Japan Institute of Heterocyclic Chemistry"}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0385-5414","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00663739","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ohta,  A"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ueki,  C"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Uchiyama,  Y"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fujimori,  K"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2015-09-28"}],"displaytype":"detail","filename":"Heterocycles_69_365_2006.pdf","filesize":[{"value":"643.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Heterocycles_69_365_2006.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/11969/files/Heterocycles_69_365_2006.pdf"},"version_id":"df1540ed-4e27-4411-8719-a690c2c9b23f"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"1,3-benzodithiolium","subitem_subject_scheme":"Other"},{"subitem_subject":"biaryl","subitem_subject_scheme":"Other"},{"subitem_subject":"redox system","subitem_subject_scheme":"Other"},{"subitem_subject":"structural change","subitem_subject_scheme":"Other"},{"subitem_subject":"electrochemistry","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis and properties of novel bis(1,3-benzodithiolium)-type dications containing a biaryl unit: New redox systems undergoing reversible structural changes by electron transfer","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis and properties of novel bis(1,3-benzodithiolium)-type dications containing a biaryl unit: New redox systems undergoing reversible structural changes by electron transfer","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1170"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2008-06-05"},"publish_date":"2008-06-05","publish_status":"0","recid":"11969","relation_version_is_last":true,"title":["Synthesis and properties of novel bis(1,3-benzodithiolium)-type dications containing a biaryl unit: New redox systems undergoing reversible structural changes by electron transfer"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:15:34.076229+00:00"}