{"created":"2021-03-01T06:14:52.393224+00:00","id":11969,"links":{},"metadata":{"_buckets":{"deposit":"cabb5085-ab59-4469-8502-47f2560f4d00"},"_deposit":{"id":"11969","owners":[],"pid":{"revision_id":0,"type":"depid","value":"11969"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00011969","sets":["1169:1170"]},"author_link":["36682","36683","36684","36685"],"item_1628147817048":{"attribute_name":"\u51fa\u7248\u30bf\u30a4\u30d7","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_6_biblio_info_6":{"attribute_name":"\u66f8\u8a8c\u60c5\u5831","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2006-12-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageStart":"365","bibliographicVolumeNumber":"69","bibliographic_titles":[{"bibliographic_title":"HETEROCYCLES"}]}]},"item_6_description_20":{"attribute_name":"\u6284\u9332","attribute_value_mlt":[{"subitem_description":"In order to develop new redox systems which undergo reversible structural changes by electron transfer, bis(1,3-benzodithiolium)-type dications (5 21) containing a biaryl unit have been synthesized by hydride abstraction of the corresponding bis(1,3-benzodithiol-2-yl)biaryis (8). Reduction of 5 2, with zinc gave the corresponding intramolecular cyclization products (6), which reverted to 5(2+) by oxidation. Cyclic voltammetry also showed the efficient interconversion between both states. X-Ray analyses revealed that the twist angle of the biaryl unit decreases largely by reductive intramolecular cyclization.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"\u8cc7\u6e90\u30bf\u30a4\u30d7\uff08\u30b3\u30f3\u30c6\u30f3\u30c4\u306e\u7a2e\u985e\uff09","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"\u5f15\u7528","attribute_value_mlt":[{"subitem_description":"HETEROCYCLES. 69(1): 365 (2006)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"\u4fe1\u5dde\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7\u3078\u306e\u30ea\u30f3\u30af","attribute_value_mlt":[{"subitem_link_text":"Ohta, A","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.uaTeOUkh.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000243651000034"}]},"item_6_publisher_4":{"attribute_name":"\u51fa\u7248\u8005","attribute_value_mlt":[{"subitem_publisher":"The Japan Institute of Heterocyclic 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change","subitem_subject_scheme":"Other"},{"subitem_subject":"electrochemistry","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"\u8a00\u8a9e","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"\u8cc7\u6e90\u30bf\u30a4\u30d7","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis and properties of novel bis(1,3-benzodithiolium)-type dications containing a biaryl unit: New redox systems undergoing reversible structural changes by electron transfer","item_titles":{"attribute_name":"\u30bf\u30a4\u30c8\u30eb","attribute_value_mlt":[{"subitem_title":"Synthesis and properties of novel bis(1,3-benzodithiolium)-type dications containing a biaryl unit: New redox systems undergoing reversible structural changes by electron 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