{"created":"2021-03-01T06:14:52.455865+00:00","id":11970,"links":{},"metadata":{"_buckets":{"deposit":"d1bf8d55-07f4-4a17-9c8a-0f7e149c1583"},"_deposit":{"id":"11970","owners":[],"pid":{"revision_id":0,"type":"depid","value":"11970"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00011970","sets":["1169:1170"]},"author_link":["36686","36687","36688"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2007","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"257","bibliographicPageStart":"251","bibliographicVolumeNumber":"74","bibliographic_titles":[{"bibliographic_title":"HETEROCYCLES"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A new type of redox-responsive molecular rotors (3(2+)/4) possessing a xylyl rotator unit have been designed and synthesized. Reduction of 3(2+) with zinc gave the corresponding cyclization products (4), from which dications (3 2,) were regenerated upon oxidation. Cyclic voltammetry also showed the interconversion between 3(2+) and 4. Variable-temperature (1)H NMR measurements revealed that the rotational barriers of the xylyl units in the neutral states (4) are higher than those in the dication states (3(2+)).","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"HETEROCYCLES. 74: 251-257 (2007)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Ohta, A","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.uaTeOUkh.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000253564900026"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Japan Institute of Heterocyclic Chemistry"}]},"item_6_relation_46":{"attribute_name":"他の資源との関係：URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://www.heterocycles.jp/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.heterocycles.jp/","subitem_relation_type_select":"URI"}}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.3987/COM-07-S(W)80"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.3987/COM-07-S(W)80","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright© 2007 The Japan Institute of Heterocyclic Chemistry"}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0385-5414","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00663739","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Uchiyama,  Y"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ohta,  A"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fujimori,  K"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2015-09-28"}],"displaytype":"detail","filename":"Heterocycles_74_251_2007.pdf","filesize":[{"value":"496.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Heterocycles_74_251_2007.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/11970/files/Heterocycles_74_251_2007.pdf"},"version_id":"a0280beb-d470-4903-9d3e-f3aa45e3baed"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis and properties of bis(1,3-benzodithiole)-type redox systems containing a xylyl rotator unit: A new type of redox-responsive molecular rotor","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis and properties of bis(1,3-benzodithiole)-type redox systems containing a xylyl rotator unit: A new type of redox-responsive molecular rotor","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1170"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2008-06-05"},"publish_date":"2008-06-05","publish_status":"0","recid":"11970","relation_version_is_last":true,"title":["Synthesis and properties of bis(1,3-benzodithiole)-type redox systems containing a xylyl rotator unit: A new type of redox-responsive molecular rotor"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:15:42.885150+00:00"}