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An NMR study of tile compound suggested that one moiety stays as a cycloheptatriene form and the other as a norcaradiene form. X-ray crystallographic analysis revealed that two methano bridges have syn- and anti-configurations to the central carbonyl bridge and also showed that one of the moieties having the syn-methano bridge stays a CHT form and the other having the anti-methano bridge stays an NCD form. (c) 2007 Elsevier Ltd. All rights reserved."}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Kuroda,  S"}], "nameIdentifiers": [{"nameIdentifier": "36725", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hirano,  I"}], "nameIdentifiers": [{"nameIdentifier": "36726", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Zhanga,  Y"}], "nameIdentifiers": [{"nameIdentifier": "36727", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Thanh,  NC"}], "nameIdentifiers": [{"nameIdentifier": "36728", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Oda,  M"}], "nameIdentifiers": [{"nameIdentifier": "36729", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "TL5811_07RevManu.pdf", "filesize": [{"value": "1.1 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 1100000.0, "url": {"label": "TL5811_07RevManu.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/11980/files/TL5811_07RevManu.pdf"}, "version_id": "3f7cd681-a7ca-4268-a7f0-eca22e618d17"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis, structure and some reactions of a multi-bridged unsaturated cyclooctadecane derivative formally having two cycloheptatrienes", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Synthesis, structure and some reactions of a multi-bridged unsaturated cyclooctadecane derivative formally having two cycloheptatrienes"}]}, "item_type_id": "6", "owner": "1", "path": ["1169/1170"], "permalink_uri": "http://hdl.handle.net/10091/487", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2007-11-13"}, "publish_date": "2007-11-13", "publish_status": "0", "recid": "11980", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis, structure and some reactions of a multi-bridged unsaturated cyclooctadecane derivative formally having two cycloheptatrienes"], "weko_shared_id": null}