{"_buckets": {"deposit": "7bb0f8ec-ab52-42ca-ba95-d796089dd6a1"}, "_deposit": {"id": "11980", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "11980"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00011980", "sets": ["1170"]}, "author_link": ["36725", "36726", "36727", "36728", "36729"], "item_1628147817048": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_6_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2007-08-13", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "33", "bibliographicPageEnd": "5815", "bibliographicPageStart": "5811", "bibliographicVolumeNumber": "48", "bibliographic_titles": [{"bibliographic_title": "Tetrahedron letters"}]}]}, "item_6_description_30": {"attribute_name": "資源タイプ（コンテンツの種類）", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_31": {"attribute_name": "フォーマット：mimeタイプ", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "TETRAHEDRON LETTERS. 48(33): 5811-5815 (2007)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "Oda, M", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.gNAmbVkm.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000248799000021"}]}, "item_6_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "PERGAMON-ELSEVIER SCIENCE LTD"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1016/j.tetlet.2007.06.096"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1016/j.tetlet.2007.06.096", "subitem_relation_type_select": "DOI"}}]}, "item_6_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0040-4039", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0040-4039", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00861801", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "cycloheptatriene-norcaradiene equilibrium; X-ray crystallographic; analysis; semi-empirical molecular orbital calculation; annulation"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "CONFORMATIONAL-ANALYSIS; CYCLOADDITION REACTIONS; VALENCE ISOMERIZATION; RINGS; NORCARADIENES; SUBSTITUENTS; EQUILIBRIUM"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "Double annulation of 1.6-bis(bromomethyl)-1,3,5-cycloheptatriene with diethyl acetonedicarboxylate under basic conditions provided the title cyclooctadecane derivative having formally two 1,3,5-cycloheptatriene moieties. An NMR study of tile compound suggested that one moiety stays as a cycloheptatriene form and the other as a norcaradiene form. X-ray crystallographic analysis revealed that two methano bridges have syn- and anti-configurations to the central carbonyl bridge and also showed that one of the moieties having the syn-methano bridge stays a CHT form and the other having the anti-methano bridge stays an NCD form. (c) 2007 Elsevier Ltd. All rights reserved."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Kuroda,  S"}], "nameIdentifiers": [{"nameIdentifier": "36725", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hirano,  I"}], "nameIdentifiers": [{"nameIdentifier": "36726", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Zhanga,  Y"}], "nameIdentifiers": [{"nameIdentifier": "36727", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Thanh,  NC"}], "nameIdentifiers": [{"nameIdentifier": "36728", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Oda,  M"}], "nameIdentifiers": [{"nameIdentifier": "36729", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "TL5811_07RevManu.pdf", "filesize": [{"value": "1.1 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 1100000.0, "url": {"label": "TL5811_07RevManu.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/11980/files/TL5811_07RevManu.pdf"}, "version_id": "3f7cd681-a7ca-4268-a7f0-eca22e618d17"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis, structure and some reactions of a multi-bridged unsaturated cyclooctadecane derivative formally having two cycloheptatrienes", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Synthesis, structure and some reactions of a multi-bridged unsaturated cyclooctadecane derivative formally having two cycloheptatrienes", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1170"], "permalink_uri": "http://hdl.handle.net/10091/487", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2007-11-13"}, "publish_date": "2007-11-13", "publish_status": "0", "recid": "11980", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis, structure and some reactions of a multi-bridged unsaturated cyclooctadecane derivative formally having two cycloheptatrienes"], "weko_shared_id": -1}