{"_buckets": {"deposit": "91a2f67c-0143-49d7-b7d5-e36ab0b73e84"}, "_deposit": {"id": "11997", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "11997"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00011997", "sets": ["1170"]}, "author_link": ["36796", "36797", "36798", "36799", "36800", "36801", "36802"], "item_1628147817048": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_6_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2005-03-01", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "2-3", "bibliographicPageEnd": "180", "bibliographicPageStart": "169", "bibliographicVolumeNumber": "78", "bibliographic_titles": [{"bibliographic_title": "MICROPOROUS AND MESOPOROUS MATERIALS"}]}]}, "item_6_description_30": {"attribute_name": "資源タイプ（コンテンツの種類）", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_31": {"attribute_name": "フォーマット：mimeタイプ", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "MICROPOROUS AND MESOPOROUS MATERIALS. 78(2-3): 169-180 (2005)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "Ishikawa, A", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.jefpOUkh.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000227164100009"}]}, "item_6_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ELSEVIER SCIENCE BV"}]}, "item_6_relation_46": {"attribute_name": "他の資源との関係：URI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "http://www.elsevier.com/wps/find/journaldescription.cws_home/600760/description#description"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://www.elsevier.com/wps/find/journaldescription.cws_home/600760/description#description", "subitem_relation_type_select": "URI"}}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1016/j.micromeso.2004.10.006"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1016/j.micromeso.2004.10.006", "subitem_relation_type_select": "DOI"}}]}, "item_6_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1387-1811", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1387-1811", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA11160707", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "spinodal; ion-exchange thermodynamics; X-ray diffraction; isotopic effect; Ab initio molecular orbital calculations"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "CRYSTAL-STRUCTURE; ION-EXCHANGE; FRACTIONATION; SODIUM; REDETERMINATION; REFINEMENT"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "The coexistence of two distinct phases, [Li-0.08(NH4)(0.92)]- and [Li-0.32(NH4)(0.68)]-A, was observed for a mixed crystal of [Li-x(NH4)(1-x)]-A of LTA (Linde type A) zeolite in the range of 0.08 \u003c x \u003c 0.32 at 295 K, where A denotes the aluminosilicate framework of LTA containing water molecules. In contrast, for x \u003c 0.08 and x \u003e 0.32, a uniform monophase was observed for the mixed crystal. The coexistence of the separated phases was deduced from ion-exchange isotherm measurements at 295 K and thermodynamic analyses. Spinodal and binodal curves were obtained. The monophasic and biphasic states were confirmed by powder X-ray diffraction. The excess Gibbs energy and the excess volume of [Li-x(NH4)(1-x)]-A were unsymmetrical with respect to x = 1/2. The Li ions favored specific ion-exchange sites. The preferential occupation of Li ions in the six-membered oxygen ring of [Li-x(NH4)(1-x)]-A was proved by Li-isotope measurements, and was demonstrated by ab initio molecular orbital calculations. The separation of two LTA-phases due to ordered Li-occupation within the six-membered oxygen rings is discussed. (C) 2004 Elsevier Inc. All rights reserved."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Ishikawa,  A"}], "nameIdentifiers": [{"nameIdentifier": "36796", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sakurazawa,  Y"}], "nameIdentifiers": [{"nameIdentifier": "36797", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shindo,  J"}], "nameIdentifiers": [{"nameIdentifier": "36798", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shimada,  M"}], "nameIdentifiers": [{"nameIdentifier": "36799", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ishimaru,  T"}], "nameIdentifiers": [{"nameIdentifier": "36800", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ishikawa,  S"}], "nameIdentifiers": [{"nameIdentifier": "36801", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sasane,  A"}], "nameIdentifiers": [{"nameIdentifier": "36802", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "A Ishikawa et al.pdf", "filesize": [{"value": "199.8 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 199800.0, "url": {"label": "A Ishikawa et al.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/11997/files/A Ishikawa et al.pdf"}, "version_id": "1599f924-e90d-4b83-961a-7dd842171a8d"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Phase separation in hydrated LTA zeolite", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Phase separation in hydrated LTA zeolite", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1170"], "permalink_uri": "http://hdl.handle.net/10091/161", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2007-04-18"}, "publish_date": "2007-04-18", "publish_status": "0", "recid": "11997", "relation": {}, "relation_version_is_last": true, "title": ["Phase separation in hydrated LTA zeolite"], "weko_shared_id": -1}