@article{oai:soar-ir.repo.nii.ac.jp:00012391, author = {Taruta, Seiichi and Iwasaki, Yoshitomo and Nishikiori, Hiromasa and Yamakami, Tomohiko and Yamaguchi, Tomohiro and Kitajima, Kunio and Okada, Kiyoshi}, issue = {7}, journal = {MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS}, month = {Apr}, note = {Transparent mica glass-ceramics were prepared by heating parent glasses that had been doped with 0.5-15 mol% CeO2. During the melting and heat treatment, Ce4+ ions in the specimens were reduced to Ce3+ ions, and one or both of these ion species were then replaced with Li+ ions in the interlayers of the separated mica crystals. However, scanning transmission electron microscope (STEM) and Z-contrast imaging revealed that the mica crystals did not contain the same amount of Ce. On excitation at 254 nm, the parent glasses and glass-ceramics emitted blue light, which originated from the 5d to 4f transition of the Ce3+ ions. The emission of the glass-ceramic containing a smaller amount of Ce was attributed to the Ce3+ ions in both the glass phase and the mica crystals, whereas that of the glass-ceramics containing a larger amount of Ce was caused mainly by Ce3+ ions in the mica crystals. The dependence of the emission band of the parent glasses on the amount of Ce was a unique feature of the Ce-doped transparent mica glass-ceramics and was not observed in previous studies of Eu-doped parent glasses and mica glass-ceramics., Article, MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS. 177(7):504-509 (2012)}, pages = {504--509}, title = {Microstructures and luminescent properties of Ce-doped transparent mica glass-ceramics}, volume = {177}, year = {2012} }