{"created":"2021-03-01T06:15:18.296342+00:00","id":12394,"links":{},"metadata":{"_buckets":{"deposit":"2a2278ec-2288-470b-8793-164e9659a3bc"},"_deposit":{"id":"12394","owners":[],"pid":{"revision_id":0,"type":"depid","value":"12394"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00012394","sets":["1221:1222"]},"author_link":["37732","37733","37734","37735","37736","37737","37738"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2012-04","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"4","bibliographicPageEnd":"591","bibliographicPageStart":"584","bibliographicVolumeNumber":"97","bibliographic_titles":[{"bibliographic_title":"POLYMER DEGRADATION AND STABILITY"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Characteristics of low temperature (473 K) dehydrochlorination of PVC powder in the presence of ZnO were studied in nitrogen flow and a reaction mechanism was proposed. It was revealed that a large portion of chlorine (ca. 70%) in PVC powder reacts with ZnO accompanying evolution of water and a slight amount of HCl (ca. 0.5%) without any organic gas. Analysis of the solid product by SEM, XRD and IR suggested that an apparent solid-solid reaction proceeds at 473 K via formation of a liquid phase which acts as reaction promoter and that the solid product is abundant in aliphatic (CH)(n) polymer. It was concluded that the first step of the dehydrochlorination is cross-linking C-C single bond formation in a polymer chain or among polymer chains followed by isomerization to polyene and aromatics.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"POLYMER DEGRADATION AND STABILITY. 97(4):584-591 (2012)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Okada, Tomohiko","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.WpDFbpkh.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_text":"Web of Science","subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000301911300015"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ELSEVIER SCI LTD"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1016/j.polymdegradstab.2012.01.009"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.polymdegradstab.2012.01.009","subitem_relation_type_select":"DOI"}}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0141-3910","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00362801","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kosuda,  Takashi"}],"nameIdentifiers":[{"nameIdentifier":"37732","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Okada,  Tomohiko"}],"nameIdentifiers":[{"nameIdentifier":"37733","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nozaka,  Shogo"}],"nameIdentifiers":[{"nameIdentifier":"37734","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Matsuzawa,  Yukitaka"}],"nameIdentifiers":[{"nameIdentifier":"37735","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shimizu,  Takuya"}],"nameIdentifiers":[{"nameIdentifier":"37736","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hamanaka,  Senji"}],"nameIdentifiers":[{"nameIdentifier":"37737","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Mishima,  Shozi"}],"nameIdentifiers":[{"nameIdentifier":"37738","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2015-09-28"}],"displaytype":"detail","filename":"Characteristics_mechanism_low_temperature_dehydrochlorination.pdf","filesize":[{"value":"714.3 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Characteristics_mechanism_low_temperature_dehydrochlorination.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/12394/files/Characteristics_mechanism_low_temperature_dehydrochlorination.pdf"},"version_id":"640b40b2-3244-40de-99b5-127ed6c134a7"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Poly(vinyl chloride)","subitem_subject_scheme":"Other"},{"subitem_subject":"Dehydrochlorination","subitem_subject_scheme":"Other"},{"subitem_subject":"Zinc(II) oxide","subitem_subject_scheme":"Other"},{"subitem_subject":"Cross-linking","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Characteristics and mechanism of low temperature dehydrochlorination of poly(vinyl chloride) in the presence of zinc(II) oxide","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Characteristics and mechanism of low temperature dehydrochlorination of poly(vinyl chloride) in the presence of zinc(II) oxide","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1222"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2012-11-20"},"publish_date":"2012-11-20","publish_status":"0","recid":"12394","relation_version_is_last":true,"title":["Characteristics and mechanism of low temperature dehydrochlorination of poly(vinyl chloride) in the presence of zinc(II) oxide"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:01:38.484366+00:00"}