{"_buckets": {"deposit": "f590e79d-2e0c-453e-9bd1-b28701774089"}, "_deposit": {"id": "12396", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "12396"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00012396", "sets": ["1222"]}, "author_link": ["37744", "37745", "37746", "37747", "37748", "37749", "37750", "37751", "37752"], "item_1628147817048": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_6_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2010-11-20", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1-3", "bibliographicPageEnd": "39", "bibliographicPageStart": "29", "bibliographicVolumeNumber": "371", "bibliographic_titles": [{"bibliographic_title": "COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS"}]}]}, "item_6_description_20": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Pore-size expansion of hexagonal-structured assembly of nanocrystalline titania (anatase) combined with cetyltrimethyammonium bromide (CH(3)(CH(2))(15)N(+)(CH(3))(3)Br(-), CTAB) (named as Hex-ncTiO(2)/CTAB Nanoskeleton) was achieved with the aid of cosolvent organic molecules (COMs). The pore-size expanded Hex-ncTiO(2)/CTAB Nanoskeleton was prepared through the sot-gel reaction of titanium oxysulfate sulfuric acid hydrate (TiOSO(4)center dot xH(2)SO(4)center dot xH(2)O, TiOSAH) in an aqueous solution initiated by CAB swollen micelles pre-prepared with the addition of COMs into aqueous CTAB micellar solutions at 60 degrees C (the product was named as Hex-ncTiO(2)/CTAB/COM Nanoskeleton). Long-chain alcohol (1-hexadecanol. C16OH), normal alkane (n-decane, C10) and benzene derivatives (benzene. Bz; 1,3,5-trimethylbenzene, TMB; 1,3,5-triethylbenzene, TEB; 1,3,5-triisopropylbenzene, TiPB) were used as COMs to evaluate the effects of COM solubilization site in CTAB micelles and COM molecular size on the pore-size expansion of the Hex-ncTiO(2)/CTAB/COM Nanoskeleton. We found that 1,3,5-trimethylbenzene (TMB) and 1,3,5-triethylbenzene (TEB) act as effective COMs for pore-size expansion of the Hex-ncTiO(2)/CTAB/COM Nanoskeleton in aqueous media. Pore sizes (average diameters) of the Hex-ncTiO(2)/CTAB/TMB Nanoskeleton and Hex-ncTiO(2)/CTAB/TEB Nanoskeleton were enlarged up to 4.2 nm and 4.3 nm, respectively, while pore size (average diameter) of the Hex-ncTiO(2)/CTAB Nanoskeleton prepared in the absence of any COMs was 2.9 nm. We also revealed that thermal stability of the Hex-ncTiO(2)/CTAB/TMB Nanoskeleton became higher than that of Hex-ncTiO(2)/CTAB Nanoskeleton. The hexagonally pore-structure of the Hex-ncTiO(2)/CTAB/TMB Nanoskeleton was retained up to 400 degrees C, while the hexagonally pore-structure of the Hex-ncTiO(2)/CTAB Nanoskeleton was kept up to 300 degrees C.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "資源タイプ（コンテンツの種類）", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS. 371(1-3):29-39 (2010)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "Sakai, Toshio", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.OhkpjFkV.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000285077600005"}]}, "item_6_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ELSEVIER SCIENCE BV"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1016/j.colsurfa.2010.08.054"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1016/j.colsurfa.2010.08.054", "subitem_relation_type_select": "DOI"}}]}, "item_6_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0927-7757", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0927-7757", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA10892561", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "Hexagonal-structured asssembly; Nanocrystalline titania; Nanoskeleton; Pore-size expansion; Cosolvent organic molecule"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "MESOPOROUS TITANIA; THIN-FILMS; CETYLTRIMETHYLAMMONIUM BROMIDE; FORMATION MECHANISM; THERMAL-STABILITY; CRYSTALLINE WALL; SOLAR-CELLS; TIO2 FILMS; PHOTOCATALYSIS; SILICAS"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "Pore-size expansion of hexagonal-structured assembly of nanocrystalline titania (anatase) combined with cetyltrimethyammonium bromide (CH(3)(CH(2))(15)N(+)(CH(3))(3)Br(-), CTAB) (named as Hex-ncTiO(2)/CTAB Nanoskeleton) was achieved with the aid of cosolvent organic molecules (COMs). The pore-size expanded Hex-ncTiO(2)/CTAB Nanoskeleton was prepared through the sot-gel reaction of titanium oxysulfate sulfuric acid hydrate (TiOSO(4)center dot xH(2)SO(4)center dot xH(2)O, TiOSAH) in an aqueous solution initiated by CAB swollen micelles pre-prepared with the addition of COMs into aqueous CTAB micellar solutions at 60 degrees C (the product was named as Hex-ncTiO(2)/CTAB/COM Nanoskeleton). Long-chain alcohol (1-hexadecanol. C16OH), normal alkane (n-decane, C10) and benzene derivatives (benzene. Bz; 1,3,5-trimethylbenzene, TMB; 1,3,5-triethylbenzene, TEB; 1,3,5-triisopropylbenzene, TiPB) were used as COMs to evaluate the effects of COM solubilization site in CTAB micelles and COM molecular size on the pore-size expansion of the Hex-ncTiO(2)/CTAB/COM Nanoskeleton. We found that 1,3,5-trimethylbenzene (TMB) and 1,3,5-triethylbenzene (TEB) act as effective COMs for pore-size expansion of the Hex-ncTiO(2)/CTAB/COM Nanoskeleton in aqueous media. Pore sizes (average diameters) of the Hex-ncTiO(2)/CTAB/TMB Nanoskeleton and Hex-ncTiO(2)/CTAB/TEB Nanoskeleton were enlarged up to 4.2 nm and 4.3 nm, respectively, while pore size (average diameter) of the Hex-ncTiO(2)/CTAB Nanoskeleton prepared in the absence of any COMs was 2.9 nm. We also revealed that thermal stability of the Hex-ncTiO(2)/CTAB/TMB Nanoskeleton became higher than that of Hex-ncTiO(2)/CTAB Nanoskeleton. The hexagonally pore-structure of the Hex-ncTiO(2)/CTAB/TMB Nanoskeleton was retained up to 400 degrees C, while the hexagonally pore-structure of the Hex-ncTiO(2)/CTAB Nanoskeleton was kept up to 300 degrees C. (C) 2010 Elsevier B.V. All rights reserved."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Sakai,  Toshio"}], "nameIdentifiers": [{"nameIdentifier": "37744", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yano,  Hanae"}], "nameIdentifiers": [{"nameIdentifier": "37745", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shibata,  Hirobumi"}], "nameIdentifiers": [{"nameIdentifier": "37746", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Endo,  Takeshi"}], "nameIdentifiers": [{"nameIdentifier": "37747", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sakamoto,  Kazutami"}], "nameIdentifiers": [{"nameIdentifier": "37748", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fukui,  Hiroshi"}], "nameIdentifiers": [{"nameIdentifier": "37749", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Koshikawa,  Naokiyo"}], "nameIdentifiers": [{"nameIdentifier": "37750", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sakai,  Hideki"}], "nameIdentifiers": [{"nameIdentifier": "37751", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Abe,  Masahiko"}], "nameIdentifiers": [{"nameIdentifier": "37752", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Pore-size_expansion_hexagonal-structured_nanocrystalline_titaniaCTAB.pdf", "filesize": [{"value": "2.0 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 2000000.0, "url": {"label": "Pore-size_expansion_hexagonal-structured_nanocrystalline_titaniaCTAB.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/12396/files/Pore-size_expansion_hexagonal-structured_nanocrystalline_titaniaCTAB.pdf"}, "version_id": "c0741ebd-69ed-414a-a22f-48ad9013f3d1"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "Hexagonal-structured asssembly", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Nanocrystalline titania", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Nanoskeleton", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Pore-size expansion", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Cosolvent organic molecule", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Pore-size expansion of hexagonal-structured nanocrystalline titania/CTAB Nanoskeleton using cosolvent organic molecules", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Pore-size expansion of hexagonal-structured nanocrystalline titania/CTAB Nanoskeleton using cosolvent organic molecules", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1222"], "permalink_uri": "http://hdl.handle.net/10091/16072", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2012-11-20"}, "publish_date": "2012-11-20", "publish_status": "0", "recid": "12396", "relation": {}, "relation_version_is_last": true, "title": ["Pore-size expansion of hexagonal-structured nanocrystalline titania/CTAB Nanoskeleton using cosolvent organic molecules"], "weko_shared_id": -1}