{"created":"2021-03-01T06:15:18.417629+00:00","id":12396,"links":{},"metadata":{"_buckets":{"deposit":"f590e79d-2e0c-453e-9bd1-b28701774089"},"_deposit":{"id":"12396","owners":[],"pid":{"revision_id":0,"type":"depid","value":"12396"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00012396","sets":["1221:1222"]},"author_link":["37744","37745","37746","37747","37748","37749","37750","37751","37752"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-11-20","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1-3","bibliographicPageEnd":"39","bibliographicPageStart":"29","bibliographicVolumeNumber":"371","bibliographic_titles":[{"bibliographic_title":"COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Pore-size expansion of hexagonal-structured assembly of nanocrystalline titania (anatase) combined with cetyltrimethyammonium bromide (CH(3)(CH(2))(15)N(+)(CH(3))(3)Br(-), CTAB) (named as Hex-ncTiO(2)/CTAB Nanoskeleton) was achieved with the aid of cosolvent organic molecules (COMs). The pore-size expanded Hex-ncTiO(2)/CTAB Nanoskeleton was prepared through the sot-gel reaction of titanium oxysulfate sulfuric acid hydrate (TiOSO(4)center dot xH(2)SO(4)center dot xH(2)O, TiOSAH) in an aqueous solution initiated by CAB swollen micelles pre-prepared with the addition of COMs into aqueous CTAB micellar solutions at 60 degrees C (the product was named as Hex-ncTiO(2)/CTAB/COM Nanoskeleton). Long-chain alcohol (1-hexadecanol. C16OH), normal alkane (n-decane, C10) and benzene derivatives (benzene. Bz; 1,3,5-trimethylbenzene, TMB; 1,3,5-triethylbenzene, TEB; 1,3,5-triisopropylbenzene, TiPB) were used as COMs to evaluate the effects of COM solubilization site in CTAB micelles and COM molecular size on the pore-size expansion of the Hex-ncTiO(2)/CTAB/COM Nanoskeleton. We found that 1,3,5-trimethylbenzene (TMB) and 1,3,5-triethylbenzene (TEB) act as effective COMs for pore-size expansion of the Hex-ncTiO(2)/CTAB/COM Nanoskeleton in aqueous media. Pore sizes (average diameters) of the Hex-ncTiO(2)/CTAB/TMB Nanoskeleton and Hex-ncTiO(2)/CTAB/TEB Nanoskeleton were enlarged up to 4.2 nm and 4.3 nm, respectively, while pore size (average diameter) of the Hex-ncTiO(2)/CTAB Nanoskeleton prepared in the absence of any COMs was 2.9 nm. We also revealed that thermal stability of the Hex-ncTiO(2)/CTAB/TMB Nanoskeleton became higher than that of Hex-ncTiO(2)/CTAB Nanoskeleton. The hexagonally pore-structure of the Hex-ncTiO(2)/CTAB/TMB Nanoskeleton was retained up to 400 degrees C, while the hexagonally pore-structure of the Hex-ncTiO(2)/CTAB Nanoskeleton was kept up to 300 degrees C.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS. 371(1-3):29-39 (2010)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Sakai, Toshio","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.OhkpjFkV.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_text":"Web of Science","subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000285077600005"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ELSEVIER SCIENCE BV"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1016/j.colsurfa.2010.08.054"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.colsurfa.2010.08.054","subitem_relation_type_select":"DOI"}}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0927-7757","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA10892561","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Sakai,  Toshio"}],"nameIdentifiers":[{"nameIdentifier":"37744","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yano,  Hanae"}],"nameIdentifiers":[{"nameIdentifier":"37745","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shibata,  Hirobumi"}],"nameIdentifiers":[{"nameIdentifier":"37746","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Endo,  Takeshi"}],"nameIdentifiers":[{"nameIdentifier":"37747","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sakamoto,  Kazutami"}],"nameIdentifiers":[{"nameIdentifier":"37748","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Fukui,  Hiroshi"}],"nameIdentifiers":[{"nameIdentifier":"37749","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Koshikawa,  Naokiyo"}],"nameIdentifiers":[{"nameIdentifier":"37750","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sakai,  Hideki"}],"nameIdentifiers":[{"nameIdentifier":"37751","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Abe,  Masahiko"}],"nameIdentifiers":[{"nameIdentifier":"37752","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2015-09-28"}],"displaytype":"detail","filename":"Pore-size_expansion_hexagonal-structured_nanocrystalline_titaniaCTAB.pdf","filesize":[{"value":"2.0 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Pore-size_expansion_hexagonal-structured_nanocrystalline_titaniaCTAB.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/12396/files/Pore-size_expansion_hexagonal-structured_nanocrystalline_titaniaCTAB.pdf"},"version_id":"c0741ebd-69ed-414a-a22f-48ad9013f3d1"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Hexagonal-structured asssembly","subitem_subject_scheme":"Other"},{"subitem_subject":"Nanocrystalline titania","subitem_subject_scheme":"Other"},{"subitem_subject":"Nanoskeleton","subitem_subject_scheme":"Other"},{"subitem_subject":"Pore-size expansion","subitem_subject_scheme":"Other"},{"subitem_subject":"Cosolvent organic molecule","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Pore-size expansion of hexagonal-structured nanocrystalline titania/CTAB Nanoskeleton using cosolvent organic molecules","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Pore-size expansion of hexagonal-structured nanocrystalline titania/CTAB Nanoskeleton using cosolvent organic molecules","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1222"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2012-11-20"},"publish_date":"2012-11-20","publish_status":"0","recid":"12396","relation_version_is_last":true,"title":["Pore-size expansion of hexagonal-structured nanocrystalline titania/CTAB Nanoskeleton using cosolvent organic molecules"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:01:38.233026+00:00"}