{"created":"2021-03-01T06:15:26.282621+00:00","id":12525,"links":{},"metadata":{"_buckets":{"deposit":"ca09493a-443f-412a-ab95-591a3db0055a"},"_deposit":{"id":"12525","owners":[],"pid":{"revision_id":0,"type":"depid","value":"12525"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00012525","sets":["1221:1222"]},"author_link":["38263","38264","38265","38266","38267"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-02","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"410","bibliographicPageStart":"405","bibliographicVolumeNumber":"247","bibliographic_titles":[{"bibliographic_title":"Physica status solidi. B, Basic solid state physics"}]}]},"item_6_description_19":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Published in Physica status solidi. B, Basic solid state physics, Vol. 247, No. 2, pp405-410, 2010.","subitem_description_type":"Other"}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Polarized reflectivity spectra of PbMoO4 crystals have been measured using synchrotron radiation up to 20 eV. The optical constants for the crystallographic axes are derived by using a Kramers-Kronig analysis. It is found that the exciton band at 3.6 eV shows a doublet structure with distinct dichroism. X-ray photoemission spectroscopy (XPS) and the calculation of the elec-tronic structure by a discrete variational Xα method are also carried out. The calculation shows that the va-lence band and the conduction band are mainly com-posed of the O 2p and Mo 4d states, respectively, and the Pb state contributes appreciably to the top of the valence band and the bottom of the conduction band. The valence-band XPS spectrum of PbMoO4 is com-pared with that of PbWO4, which reveals a remarkable difference between them. This difference reflects dif-ferent magnitude of hybridization of Mo 4d or W 5d state to the valence band. The exciton transition is ex-plained in terms of the cationic Pb 6s → 6p excitation model taking into account the crystal-field splitting and the spin-orbit interaction of Pb 6p state. From a comparison of the doublet structure of the exciton band of PbMoO4 and PbWO4, it is suggested that the electron-hole exchange interaction plays an important role for the exciton transitions in both materials.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Physica status solidi. B, Basic solid state physics. 247(2):405-410 (2010)","subitem_description_type":"Other"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"WILEY-VCH Verlag GmbH & Co."}]},"item_6_relation_46":{"attribute_name":"他の資源との関係：URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://www.interscience.wiley.com/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.interscience.wiley.com/","subitem_relation_type_select":"URI"}}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1002/pssb.200945447"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/pssb.200945447","subitem_relation_type_select":"DOI"}}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0370-1972","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12238694","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Fujita,  M"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Itoh,  M"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Mitani,  H"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sangeeta"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tyagi,  Mohit"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2015-09-28"}],"displaytype":"detail","filename":"PSSb投稿原稿.pdf","filesize":[{"value":"334.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"PSSb投稿原稿.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/12525/files/PSSb投稿原稿.pdf"},"version_id":"bc4b5bc1-424e-4614-84d4-85ae7f1e69fa"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Exciton transition and electronic structure of PbMoO4 crystals studied by polarized light","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Exciton transition and electronic structure of PbMoO4 crystals studied by polarized light","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1222"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2010-01-25"},"publish_date":"2010-01-25","publish_status":"0","recid":"12525","relation_version_is_last":true,"title":["Exciton transition and electronic structure of PbMoO4 crystals studied by polarized light"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:30:20.587828+00:00"}