{"created":"2021-03-01T06:16:14.311276+00:00","id":13313,"links":{},"metadata":{"_buckets":{"deposit":"c82326ff-6142-4606-a38b-8f39a08a9b21"},"_deposit":{"id":"13313","owners":[],"pid":{"revision_id":0,"type":"depid","value":"13313"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00013313","sets":["1309:1310"]},"author_link":["40338","40339","40340","40341"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-08","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"22","bibliographicPageEnd":"96","bibliographicPageStart":"84","bibliographicVolumeNumber":"484","bibliographic_titles":[{"bibliographic_title":"Applied Catalysis A"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Multiwall carbon nanotubes (MWCNTs)/ruthenium dioxide nanoparticles (RuO2NPs) composite was prepared by a straightforward ‘dry synthesis’ method. After being well characterized, the prepared composite was used as a nanocatalyst (RuO2/MWCNT) for the transfer hydrogenation of carbonyl compounds. The excellent adhesion of RuO2NPs on the anchoring sites of MWCNTs was confirmed by TEM and Raman analyses. The weight percentage (7.97 wt%) and the chemical state (+4) of Ru in RuO2/MWCNT was confirmed by EDS and XPS analyses, respectively. It was found that the RuO2/MWCNT has a higher specific surface area of 189.3 m2 g?1. Initially the reaction conditions were optimized and then the scope of the catalytic system was extended with a wide range of carbonyl compounds. The influence of the size of RuO2NPs on the transfer hydrogenation of carbonyl compounds was also studied. The RuO2/MWCNT is highly chemoselective, heterogeneous in nature, reusable and highly stable. Owing to the high stability of the used catalyst (u-RuO2/MWCNT), it was further calcinated at high temperature to obtain RuO2 nanorods (NRs) hybrid MWCNTs. Then the hybrid material was used as a catalyst (r-RuO2/MWCNT) for the aerial oxidation of alcohols and the result was found to be good.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Applied Catalysis A. 484(22):84-96 (2014)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Kim, I.S.","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.jNyCjFkV.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000342476700012"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ELSEVIER"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1016/j.apcata.2014.06.032"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.apcata.2014.06.032","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright© 2014 Elsevier B.V."}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0926-860X","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA10821202","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Gopiraman,  M"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Babu,  S. Ganesh"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Karvembu,  R"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kim,  I.S."}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2015-09-28"}],"displaytype":"detail","filename":"140_Nanostructured_RuO2_MWCNTs_Efficient_catalyst.pdf","filesize":[{"value":"1.5 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"140_Nanostructured_RuO2_MWCNTs_Efficient_catalyst.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/13313/files/140_Nanostructured_RuO2_MWCNTs_Efficient_catalyst.pdf"},"version_id":"aab32d7d-4f8b-46b6-be42-4a764eb3e4ec"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"MWCNTs","subitem_subject_scheme":"Other"},{"subitem_subject":"RuO2 nanostructures","subitem_subject_scheme":"Other"},{"subitem_subject":"Dry synthesis","subitem_subject_scheme":"Other"},{"subitem_subject":"Heterogeneous catalyst","subitem_subject_scheme":"Other"},{"subitem_subject":"Transfer hydrogenation","subitem_subject_scheme":"Other"},{"subitem_subject":"Aerial oxidation","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Nanostructured RuO2 on MWCNTs: Efficient catalyst for transfer hydrogenation of carbonyl compounds and aerial oxidation of alcohols","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Nanostructured RuO2 on MWCNTs: Efficient catalyst for transfer hydrogenation of carbonyl compounds and aerial oxidation of alcohols","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1310"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2014-08-25"},"publish_date":"2014-08-25","publish_status":"0","recid":"13313","relation_version_is_last":true,"title":["Nanostructured RuO2 on MWCNTs: Efficient catalyst for transfer hydrogenation of carbonyl compounds and aerial oxidation of alcohols"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:03:27.990015+00:00"}