{"_buckets": {"deposit": "5b9fb873-6d4a-4ba9-9f67-5b99d0f6e4bd"}, "_deposit": {"id": "13361", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "13361"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00013361", "sets": ["1310"]}, "author_link": ["40560", "40561", "40562"], "item_1628147817048": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_6_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2013-01-15", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "231", "bibliographicPageStart": "222", "bibliographicVolumeNumber": "252", "bibliographic_titles": [{"bibliographic_title": "Journal of Photochemistry and Photobiology A: Chemistry"}]}]}, "item_6_description_20": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Peroxyoxalate chemiluminescence (PO-CL) was investigated using eight oxalates with various phenol moieties and the distyrylbenzene (DSB) fluorophores with various substituents. The ρ-values in the Hammett correlation between the substituent constants (σp+) of the DSBs and the singlet chemiexcitation yields (ΦS) for the PO-CL reactions varied from −0.50 to −1.01 depending on the oxalate structure, and the reactive oxalates tended to afford the higher absolute ρ-values but with a few exceptions. Based on the CIEEL mechanism, these experimental observations suggest that the aryloxy groups still remain in the 1,2-dioxetanones (DOTs), which are the postulated high-energy intermediates, and control the electronic properties of DOTs as electron-acceptors. The LUMO energies of the DOTs calculated by the ab initio method with a B3LYP/6-31g(d) basis set reveal that the lower the DOT-LUMO energies, the higher the absolute ρ-values were provided for the corresponding oxalates, as predicted by the frontier molecular orbital (FMO) theory. Thus, the chemical species interacting with the DSBs would be not unitary and will be DOTs.", "subitem_description_type": "Abstract"}]}, "item_6_description_30": {"attribute_name": "資源タイプ（コンテンツの種類）", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_6_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "Journal of Photochemistry and Photobiology A: Chemistry. 252:222-231 (2013)", "subitem_description_type": "Other"}]}, "item_6_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "Motoyoshiya, Jiro", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.WeymjekV.html"}]}, "item_6_link_67": {"attribute_name": "WoS", "attribute_value_mlt": [{"subitem_link_text": "Web of Science", "subitem_link_url": "http://gateway.isiknowledge.com/gateway/Gateway.cgi?\u0026GWVersion=2\u0026SrcAuth=ShinshuUniv\u0026SrcApp=ShinshuUniv\u0026DestLinkType=FullRecord\u0026DestApp=WOS\u0026KeyUT=000314480800029"}]}, "item_6_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ELSEVIER"}]}, "item_6_relation_48": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "10.1016/j.jphotochem.2012.12.006"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1016/j.jphotochem.2012.12.006", "subitem_relation_type_select": "DOI"}}]}, "item_6_rights_62": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "Copyright © 2013 Elsevier B.V."}]}, "item_6_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_6_source_id_35": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1010-6030", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_39": {"attribute_name": "NII ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1010-6030", "subitem_source_identifier_type": "ISSN"}]}, "item_6_source_id_40": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA10684407", "subitem_source_identifier_type": "NCID"}]}, "item_6_text_69": {"attribute_name": "wosonly authkey", "attribute_value_mlt": [{"subitem_text_value": "Peroxyoxalate chemiluminescence; Hammett correlation; High-energy intermediate; Frontier molecular orbital theory"}]}, "item_6_text_70": {"attribute_name": "wosonly keywords", "attribute_value_mlt": [{"subitem_text_value": "MAGNETIC-RESONANCE-SPECTROSCOPY; HYDROGEN-PEROXIDE; CHEMI-LUMINESCENCE; FLUORESCENT COMPOUNDS; REACTION-MECHANISM; KINETICS; SYSTEM; BIS(PENTACHLOROPHENYL)OXALATE; CHEMIEXCITATION; INTERMEDIATE"}]}, "item_6_textarea_68": {"attribute_name": "wosonly abstract", "attribute_value_mlt": [{"subitem_textarea_value": "Peroxyoxalate chemiluminescence (PO-CL) was investigated using eight oxalates with various phenol moieties and the distyrylbenzene (DSB) fluorophores with various substituents. The rho-values in the Hammett correlation between the substituent constants (sigma(+)(p)) of the DSBs and the singlet chemiexcitation yields (Phi(s)) for the PO-CL reactions varied from -0.50 to -1.01 depending on the oxalate structure, and the reactive oxalates tended to afford the higher absolute rho-values but with a few exceptions. Based on the CIEEL mechanism, these experimental observations suggest that the aryloxy groups still remain in the 1,2-dioxetanones (DOTs), which are the postulated high-energy intermediates, and control the electronic properties of DOTs as electron-acceptors. The LUMO energies of the DOTs calculated by the ab initio method with a B3LYP/6-31g(d) basis set reveal that the lower the DOT-LUMO energies, the higher the absolute rho-values were provided for the corresponding oxalates, as predicted by the frontier molecular orbital (FMO) theory. Thus, the chemical species interacting with the DSBs would be not unitary and will be DOTs. (C) 2012 Elsevier B.V. All rights reserved."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Maruyama,  Takayuki"}], "nameIdentifiers": [{"nameIdentifier": "40560", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Narita,  Susumu"}], "nameIdentifiers": [{"nameIdentifier": "40561", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Motoyoshiya,  Jiro"}], "nameIdentifiers": [{"nameIdentifier": "40562", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Hammett_correlation_between_distyrylbenzene_substituents_chemiluminescence_efficiency.pdf", "filesize": [{"value": "1.9 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 1900000.0, "url": {"label": "Hammett_correlation_between_distyrylbenzene_substituents_chemiluminescence_efficiency.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/13361/files/Hammett_correlation_between_distyrylbenzene_substituents_chemiluminescence_efficiency.pdf"}, "version_id": "4a2d8983-f4d3-4a20-a65e-bdc8bc9eeebd"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "Peroxyoxalate chemiluminescence", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Hammett correlation", "subitem_subject_scheme": "Other"}, {"subitem_subject": "High-energy intermediate", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Frontier molecular orbital theory", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "The Hammett correlation between distyrylbenzene substituents and chemiluminescence efficiency providing various ρ-values for peroxyoxalate chemiluminescence of several oxalates", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "The Hammett correlation between distyrylbenzene substituents and chemiluminescence efficiency providing various ρ-values for peroxyoxalate chemiluminescence of several oxalates", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1310"], "permalink_uri": "http://hdl.handle.net/10091/16796", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2013-03-14"}, "publish_date": "2013-03-14", "publish_status": "0", "recid": "13361", "relation": {}, "relation_version_is_last": true, "title": ["The Hammett correlation between distyrylbenzene substituents and chemiluminescence efficiency providing various ρ-values for peroxyoxalate chemiluminescence of several oxalates"], "weko_shared_id": -1}