@article{oai:soar-ir.repo.nii.ac.jp:00013410, author = {Yoshida, Eri and Yamashita, Daisuke and Sakai, Ryo and Tanabe, Yoo and Nishii, Yoshinori}, issue = {15}, journal = {SYNLETT}, month = {Sep}, note = {We achieved the first total synthesis of a novel (+/-)-6'-methoxyretrojusticidin B, which was proposed as procumphthalide A, utilizing regiocontrolled benzannulation of an aryl(aryl')-2,2-dichlorocyclopropylmethanol as the key step. (1)H NMR spectral data suggested that the structure of the synthesized product, 6'-methoxyretrojusticidin B, was inconsistent with that of natural procumphthalide A. A computational study of the rotational barrier rationally supports the existence of a rigid chiral axis in 6'-methoxyretrojusticidin B. The revised structural elucidation of natural procumphthalide A was concluded to be 5'-methoxyretrochinensin., Article, SYNLETT. 2010(15):2275-2278 (2010)}, pages = {2275--2278}, title = {First Total Synthesis of (+/-)-6 '-Methoxyretrojusticidin B Using Regiocontrolled Benzannulation: Structural Inconsistency with Procumphthalide A and Its Revision to 5 '-Methoxyretrochinensin}, volume = {2010}, year = {2010} }