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The reduction of both compounds with tin(II) chloride in acidic media was accompanied by acid hydrolysis that produced emodin anthrone, whose oxidative dimerization with iron (III) chloride hydrate gave the bianthrone in high yield. The oxidation of the bianthrone in the presence of Nethyldiisopropylamine gave protohypericin, which was converted into hypericin upon irradiation."}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Motoyoshiya, J"}], "nameIdentifiers": [{"nameIdentifier": "41447", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Masue, Y"}], "nameIdentifiers": [{"nameIdentifier": "41448", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nishi, Y"}], "nameIdentifiers": [{"nameIdentifier": "41449", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Aoyama, H"}], "nameIdentifiers": [{"nameIdentifier": "41450", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "P751112RR.pdf", "filesize": [{"value": "106.7 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 106700.0, "url": {"label": "P751112RR.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/13548/files/P751112RR.pdf"}, "version_id": "2e3f779f-bd54-4770-9f35-5a88521cf4a8"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis of hypericin via emodin anthrone derived from a two-fold diels-alder reaction of 1,4-benzoquinone", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Synthesis of hypericin via emodin anthrone derived from a two-fold diels-alder reaction of 1,4-benzoquinone", "subitem_title_language": "en"}]}, "item_type_id": "6", "owner": "1", "path": ["1310"], "permalink_uri": "http://hdl.handle.net/10091/518", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2007-11-16"}, "publish_date": "2007-11-16", "publish_status": "0", "recid": "13548", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis of hypericin via emodin anthrone derived from a two-fold diels-alder reaction of 1,4-benzoquinone"], "weko_shared_id": -1}
Synthesis of hypericin via emodin anthrone derived from a two-fold diels-alder reaction of 1,4-benzoquinone
http://hdl.handle.net/10091/518
http://hdl.handle.net/10091/51872706271-e1c7-4218-92d6-a2b885285051
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2007-11-16 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Synthesis of hypericin via emodin anthrone derived from a two-fold diels-alder reaction of 1,4-benzoquinone | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Motoyoshiya, J
× Motoyoshiya, J× Masue, Y× Nishi, Y× Aoyama, H |
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信州大学研究者総覧へのリンク | ||||||
氏名 | Motoyoshiya, J | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.WeymjekV.html | |||||
出版者 | ||||||
出版者 | Synthesis of hypericin via emodin anthrone derived from a two-fold diels-alder reaction of 1,4-benzoquinone | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Natural Product Communications. 2(1):67-70 (2007) | |||||
書誌情報 |
Natural Product Communications 巻 2, 号 1, p. 67-70, 発行日 2007 |
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内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | This is a preprint of an article published in Natural Product Communications. 2(1):67-70 (2007). | |||||
アドレス | ||||||
内容記述タイプ | Other | |||||
内容記述 | http://www.naturalproduct.us/ | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 1934-578X | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1177/1934578X0700200113 | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
WoS | ||||||
表示名 | Web of Science | |||||
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