@techreport{oai:soar-ir.repo.nii.ac.jp:00014458, author = {杉本, 渉}, month = {Mar}, note = {Oxide nanosheet colloids can be utilized as structure building units for novel functional materials. The purpuse of this study is the utilization of the such nanosheet colloids for the fabrication of porous orgamic-inorganic hybrids and electrode materials. The structure of a new ethylenediamine- H2Ti4O9 acid compound, which was obtained by self-assembly of H2Ti409 nanosheet colloids and ethylenediamine, was studied by SEM, XRD, TG-DTA, and solid state 13C-NMR. Two types of ethylenediamine-H2Ti4O9 intercalation compounds, namely, compounds with ethylenediamine in a mono-layer or a bi-layer arrangement, could be prepared depending on the synthetic conditions. The latter composite material is a novel intercalation compound with the ethylenediamine arranged in a bi-layer with one amine group attached to the interlayer surface of H2Ti4O9 as an ammonium cation (-NH3+) and the other group present in the interlayer space in a neutral state (-NH2)., Article, 先進ファイバー工学研究教育拠点研究成果報告書 11: 36-36(2005)}, title = {15-1-11 : 酸化物ナノシートコロイドを利用した機能性材料}, year = {2005} }