@techreport{oai:soar-ir.repo.nii.ac.jp:00014491, author = {濱田, 州博 and 平井, 利博 and 白井, 汪芳 and 山田, 竜二}, month = {Mar}, note = {Various types of bolaform electrolytes and gemini surfactants were designed and prepared. Their behavior was investigated using UV absorption spectroscopy and conductance measurements. The binding of acid dyes with them in aqueous solutions, their effects on the binding of acid dyes with water-soluble polymers, and their effects on the sorption of acid and direct dyes with nylon 6, silk, wool, and cotton were studied in detail. As a result, it is found that not only the terminal groups but also the spacer groups play an imporlant role in the auxiliary effects. Furthermore, some bolaform electrolytes containing a benzene ring as a spacer group can form supramolecular aggregates, which consist of one bolaform electrolyte and two dyes. Thus the adequate design of bolaform electrolytes is believed to lead to the formation of novel supramolecular aggregate. This is the first step towards the development of supramolecular dyeing procedure, and as the second step. such supramolecular aggregates would be introduced into polymer matrices and fibers., Article, 先進ファイバー工学研究教育拠点研究成果報告書 11: 82-82(2005)}, title = {15-3-15 : 染料と助剤の高次錯合体を繊維中に構築する超分子染色加工法の開発}, year = {2005} }