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Those could be applied as emulsifiers for emulsion polymerization. It was found that UV-irradiation of the resulting latexes precipitates polymers almost quantitatively and removes surface-active or ionic residues from the polymer precipitates. We also prepared acylbenzyl-containing surfactants which were sensitive with longer-wavelength light (> 280 nm) and examined their degradability and functionality. Rapid and selective dechlorination of trichlorobenzene (TCB) was performed in aqueous surfactant solutions in the presence of photosensitizers (dimethylaniline derivatives) and sacrificial reductants. 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