@techreport{oai:soar-ir.repo.nii.ac.jp:00014509,
 author = {太田,  和親 and 松瀬,  丈浩 and 木村,  睦 and 宇佐美,  久尚},
 month = {Mar},
 note = {It took extremely short reaction time only for 10min. to synthesize the long alkylthio-group-substituted metal-free compound, (C_8S)_8PcH_2(1), by the present microwave method giving significantly high yield(71 %), although it took very long reaction time for 20-24hrs to synthesize (C_8S)_8PcH_2(1), by the conventional oil bath method, It is noteworthy that this is the first example of syntheses of metal-free Pc derivatives in an organic solvent by microwave method. When the metal complexes. (C_8S)_8PcCu(2) and (C<_12>O)_8PcCu(6), were synthesized by microwave method, the optimal condition and the best yield depended very much on the kind of copper salts. Template effect of metal could not be seen in syntheses of the alkylthi0-group-substituted copper complex, (C_8S)_8PcCu(2), by microwave method. Oh the other hand, the template effect of metal could be seen in the cases of both (C_<12>O)_8PcCu(6) having alkoxy groups and the core complex PcCu. This difference may be attributed to difference of the intermediates. Further studies are necessary to clarify the hypothesis., Article, 先進ファイバー工学研究教育拠点研究成果報告書 11: 108-109(2005)},
 title = {16-4-10 : 光伝導性液晶半導体の高速合成と自発配向試料の開発},
 year = {2005}
}