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These compounds possess a L-lysine derivative as a self-organizing segment. Viologen 1 and 2 formed gels in aromatic solvents (benzene, toluene, nitrobenzene, chlorobenzene), while they precipitated in alcohols. In DMF, DMSO, and chloroform, both viologens have a high solubility and give an isotropic solution. TEM images of samples prepared from these solvents demonstrated that the viologens formed nanometer-scaled assemblies in aromatic solvents and alcohols, but not in chloroform. In toluene, 1 and 2 had a nanofiber with ca. 250- 700 nm width and nanoribbon with ca. 300- 400 nm width, formed by entangling of fine fibers (ca. 30 -IOO nm width) or ribbons (ca. 70-200 nm width). It is noteworthy that the viologens created different nanostructures; a fibrous structure for 1 and a ribbon structure for 2. On the other hand, Ru2 has a gelation ability for some aromatic solvents, but Ru1 gave isotropic solutions for these solvents. The minimum gelation concentration of Ru2 is 2 mg/ml for benzene and 4 mg/ml for toluene. The TEM images of Ru1 and Ru2 prepared from toluene showed that Ru1 and Ru2 formed a nanofiber structure. Ru2 created the network by entanglement of fine fibers , and such a hierarchical network structure is responsible for the gelation behavior of Ru2. In contrast, Ru1 forms a helical structure.", "subitem_description_type": "Abstract"}]}, "item_11_description_30": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7\uff08\u30b3\u30f3\u30c6\u30f3\u30c4\u306e\u7a2e\u985e\uff09", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_11_description_5": {"attribute_name": "\u5f15\u7528", "attribute_value_mlt": [{"subitem_description": "\u5148\u9032\u30d5\u30a1\u30a4\u30d0\u30fc\u5de5\u5b66\u7814\u7a76\u6559\u80b2\u62e0\u70b9\u7814\u7a76\u6210\u679c\u5831\u544a\u66f8 10: 29-30(2004)", "subitem_description_type": "Other"}]}, "item_11_link_3": {"attribute_name": "\u4fe1\u5dde\u5927\u5b66\u7814\u7a76\u8005\u7dcf\u89a7\u3078\u306e\u30ea\u30f3\u30af", "attribute_value_mlt": [{"subitem_link_text": "\u9234\u6728, \u6b63\u6d69", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.WVnmjFkV.html"}, {"subitem_link_text": "\u767d\u4e95, \u6c6a\u82b3", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.jUcVjCkV.html"}, {"subitem_link_text": "\u82f1, \u8b19\u4e8c", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.WCyNjekV.html"}]}, "item_11_publisher_4": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "\u4fe1\u5dde\u5927\u5b66\u7e4a\u7dad\u5b66\u90e8"}]}, "item_11_select_64": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_11_source_id_40": {"attribute_name": "\u66f8\u8a8c\u30ec\u30b3\u30fc\u30c9ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA1200368X", "subitem_source_identifier_type": "NCID"}]}, "item_11_text_66": {"attribute_name": "sortkey", "attribute_value_mlt": [{"subitem_text_value": "004"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "\u9234\u6728,  \u6b63\u6d69"}], "nameIdentifiers": [{"nameIdentifier": "43889", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "\u767d\u4e95,  \u6c6a\u82b3"}], "nameIdentifiers": [{"nameIdentifier": "43890", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "\u82f1,  \u8b19\u4e8c"}], "nameIdentifiers": [{"nameIdentifier": "43891", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "filename": "AFSTT10-104.pdf", "filesize": [{"value": "906.0 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 9060000, "url": {"label": "AFSTT10-104.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/14566/files/AFSTT10-104.pdf"}, "version_id": "a366bafe-8456-4033-9799-1c297b9348f4"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "research report", "resourceuri": "http://purl.org/coar/resource_type/c_18ws"}]}, "item_title": "15-1-4 :\u81ea\u5df1\u96c6\u5408\u80fd\u3092\u6301\u3064Ru(II)\u932f\u4f53\u3068\u30d3\u30aa\u30ed\u30b0\u30f3\u3092\u542b\u3080\u30ca\u30ce\u30d5\u30a1\u30a4\u30d0\u30fc\u306e\u5275\u88fd", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "15-1-4 :\u81ea\u5df1\u96c6\u5408\u80fd\u3092\u6301\u3064Ru(II)\u932f\u4f53\u3068\u30d3\u30aa\u30ed\u30b0\u30f3\u3092\u542b\u3080\u30ca\u30ce\u30d5\u30a1\u30a4\u30d0\u30fc\u306e\u5275\u88fd"}]}, "item_type_id": "11", "owner": "1", "path": ["1309/1314/1458/1462"], "permalink_uri": "http://hdl.handle.net/10091/13543", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2012-02-23"}, "publish_date": "2012-02-23", "publish_status": "0", "recid": "14566", "relation": {}, "relation_version_is_last": true, "title": ["15-1-4 :\u81ea\u5df1\u96c6\u5408\u80fd\u3092\u6301\u3064Ru(II)\u932f\u4f53\u3068\u30d3\u30aa\u30ed\u30b0\u30f3\u3092\u542b\u3080\u30ca\u30ce\u30d5\u30a1\u30a4\u30d0\u30fc\u306e\u5275\u88fd"], "weko_shared_id": null}