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  1. 080 繊維学部
  2. 0802 紀要・刊行物
  3. 08030 先端繊維技術科学に関する研究報告
  4. Vol. 10

15-1-4 :自己集合能を持つRu(II)錯体とビオログンを含むナノファイバーの創製

http://hdl.handle.net/10091/13543
http://hdl.handle.net/10091/13543
66873ff8-46bd-41e7-82b6-13802a92c073
名前 / ファイル ライセンス アクション
AFSTT10-104.pdf AFSTT10-104.pdf (906.0 kB)
Item type 研究報告書 / Research Paper(1)
公開日 2012-02-23
タイトル
言語 ja
タイトル 15-1-4 :自己集合能を持つRu(II)錯体とビオログンを含むナノファイバーの創製
言語
言語 jpn
資源タイプ
資源 http://purl.org/coar/resource_type/c_18ws
タイプ research report
その他(別言語等)のタイトル
その他のタイトル 有機ナノファーバーの形成と応用
著者 鈴木, 正浩

× 鈴木, 正浩

WEKO 43889

鈴木, 正浩

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白井, 汪芳

× 白井, 汪芳

WEKO 43890

白井, 汪芳

Search repository
英, 謙二

× 英, 謙二

WEKO 43891

英, 謙二

Search repository
信州大学研究者総覧へのリンク
氏名 鈴木, 正浩
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.WVnmjFkV.html
信州大学研究者総覧へのリンク
氏名 白井, 汪芳
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.jUcVjCkV.html
信州大学研究者総覧へのリンク
氏名 英, 謙二
URL http://soar-rd.shinshu-u.ac.jp/profile/ja.WCyNjekV.html
出版者
出版者 信州大学繊維学部
引用
内容記述タイプ Other
内容記述 先進ファイバー工学研究教育拠点研究成果報告書 10: 29-30(2004)
書誌情報 先進ファイバー工学研究教育拠点研究成果報告書

巻 10, p. 29-30, 発行日 2004-03-31
抄録
内容記述タイプ Abstract
内容記述 We have synthesized new Ru(II) complexes and viologen derivatives and studied the self-assembling and gelation properties in various organic solvents. These compounds possess a L-lysine derivative as a self-organizing segment. Viologen 1 and 2 formed gels in aromatic solvents (benzene, toluene, nitrobenzene, chlorobenzene), while they precipitated in alcohols. In DMF, DMSO, and chloroform, both viologens have a high solubility and give an isotropic solution. TEM images of samples prepared from these solvents demonstrated that the viologens formed nanometer-scaled assemblies in aromatic solvents and alcohols, but not in chloroform. In toluene, 1 and 2 had a nanofiber with ca. 250- 700 nm width and nanoribbon with ca. 300- 400 nm width, formed by entangling of fine fibers (ca. 30 -IOO nm width) or ribbons (ca. 70-200 nm width). It is noteworthy that the viologens created different nanostructures; a fibrous structure for 1 and a ribbon structure for 2. On the other hand, Ru2 has a gelation ability for some aromatic solvents, but Ru1 gave isotropic solutions for these solvents. The minimum gelation concentration of Ru2 is 2 mg/ml for benzene and 4 mg/ml for toluene. The TEM images of Ru1 and Ru2 prepared from toluene showed that Ru1 and Ru2 formed a nanofiber structure. Ru2 created the network by entanglement of fine fibers , and such a hierarchical network structure is responsible for the gelation behavior of Ru2. In contrast, Ru1 forms a helical structure.
資源タイプ(コンテンツの種類)
内容記述タイプ Other
内容記述 Article
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA1200368X
出版タイプ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
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