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15-1-4 :自己集合能を持つRu(II)錯体とビオログンを含むナノファイバーの創製
http://hdl.handle.net/10091/13543
http://hdl.handle.net/10091/1354366873ff8-46bd-41e7-82b6-13802a92c073
名前 / ファイル | ライセンス | アクション |
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Item type | 研究報告書 / Research Paper(1) | |||||
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公開日 | 2012-02-23 | |||||
タイトル | ||||||
言語 | ja | |||||
タイトル | 15-1-4 :自己集合能を持つRu(II)錯体とビオログンを含むナノファイバーの創製 | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_18ws | |||||
タイプ | research report | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | 有機ナノファーバーの形成と応用 | |||||
著者 |
鈴木, 正浩
× 鈴木, 正浩× 白井, 汪芳× 英, 謙二 |
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信州大学研究者総覧へのリンク | ||||||
氏名 | 鈴木, 正浩 | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.WVnmjFkV.html | |||||
信州大学研究者総覧へのリンク | ||||||
氏名 | 白井, 汪芳 | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.jUcVjCkV.html | |||||
信州大学研究者総覧へのリンク | ||||||
氏名 | 英, 謙二 | |||||
URL | http://soar-rd.shinshu-u.ac.jp/profile/ja.WCyNjekV.html | |||||
出版者 | ||||||
出版者 | 信州大学繊維学部 | |||||
引用 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 先進ファイバー工学研究教育拠点研究成果報告書 10: 29-30(2004) | |||||
書誌情報 |
先進ファイバー工学研究教育拠点研究成果報告書 巻 10, p. 29-30, 発行日 2004-03-31 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | We have synthesized new Ru(II) complexes and viologen derivatives and studied the self-assembling and gelation properties in various organic solvents. These compounds possess a L-lysine derivative as a self-organizing segment. Viologen 1 and 2 formed gels in aromatic solvents (benzene, toluene, nitrobenzene, chlorobenzene), while they precipitated in alcohols. In DMF, DMSO, and chloroform, both viologens have a high solubility and give an isotropic solution. TEM images of samples prepared from these solvents demonstrated that the viologens formed nanometer-scaled assemblies in aromatic solvents and alcohols, but not in chloroform. In toluene, 1 and 2 had a nanofiber with ca. 250- 700 nm width and nanoribbon with ca. 300- 400 nm width, formed by entangling of fine fibers (ca. 30 -IOO nm width) or ribbons (ca. 70-200 nm width). It is noteworthy that the viologens created different nanostructures; a fibrous structure for 1 and a ribbon structure for 2. On the other hand, Ru2 has a gelation ability for some aromatic solvents, but Ru1 gave isotropic solutions for these solvents. The minimum gelation concentration of Ru2 is 2 mg/ml for benzene and 4 mg/ml for toluene. The TEM images of Ru1 and Ru2 prepared from toluene showed that Ru1 and Ru2 formed a nanofiber structure. Ru2 created the network by entanglement of fine fibers , and such a hierarchical network structure is responsible for the gelation behavior of Ru2. In contrast, Ru1 forms a helical structure. | |||||
資源タイプ(コンテンツの種類) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Article | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA1200368X | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |