{"_buckets": {"deposit": "91347907-cedb-4f17-94f1-b3e6735fd6a7"}, "_deposit": {"id": "14566", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "14566"}, "status": "published"}, "_oai": {"id": "oai:soar-ir.repo.nii.ac.jp:00014566", "sets": ["1462"]}, "author_link": ["43889", "43890", "43891"], "item_11_alternative_title_1": {"attribute_name": "その他（別言語等）のタイトル", "attribute_value_mlt": [{"subitem_alternative_title": "有機ナノファーバーの形成と応用"}]}, "item_11_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2004-03-31", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "30", "bibliographicPageStart": "29", "bibliographicVolumeNumber": "10", "bibliographic_titles": [{"bibliographic_title": "先進ファイバー工学研究教育拠点研究成果報告書"}]}]}, "item_11_description_20": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "We have synthesized new Ru(II) complexes and viologen derivatives and studied the self-assembling and gelation properties in various organic solvents. These compounds possess a L-lysine derivative as a self-organizing segment. Viologen 1 and 2 formed gels in aromatic solvents (benzene, toluene, nitrobenzene, chlorobenzene), while they precipitated in alcohols. In DMF, DMSO, and chloroform, both viologens have a high solubility and give an isotropic solution. TEM images of samples prepared from these solvents demonstrated that the viologens formed nanometer-scaled assemblies in aromatic solvents and alcohols, but not in chloroform. In toluene, 1 and 2 had a nanofiber with ca. 250- 700 nm width and nanoribbon with ca. 300- 400 nm width, formed by entangling of fine fibers (ca. 30 -IOO nm width) or ribbons (ca. 70-200 nm width). It is noteworthy that the viologens created different nanostructures; a fibrous structure for 1 and a ribbon structure for 2. On the other hand, Ru2 has a gelation ability for some aromatic solvents, but Ru1 gave isotropic solutions for these solvents. The minimum gelation concentration of Ru2 is 2 mg/ml for benzene and 4 mg/ml for toluene. The TEM images of Ru1 and Ru2 prepared from toluene showed that Ru1 and Ru2 formed a nanofiber structure. Ru2 created the network by entanglement of fine fibers , and such a hierarchical network structure is responsible for the gelation behavior of Ru2. In contrast, Ru1 forms a helical structure.", "subitem_description_type": "Abstract"}]}, "item_11_description_30": {"attribute_name": "資源タイプ（コンテンツの種類）", "attribute_value_mlt": [{"subitem_description": "Article", "subitem_description_type": "Other"}]}, "item_11_description_5": {"attribute_name": "引用", "attribute_value_mlt": [{"subitem_description": "先進ファイバー工学研究教育拠点研究成果報告書 10: 29-30(2004)", "subitem_description_type": "Other"}]}, "item_11_link_3": {"attribute_name": "信州大学研究者総覧へのリンク", "attribute_value_mlt": [{"subitem_link_text": "鈴木, 正浩", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.WVnmjFkV.html"}, {"subitem_link_text": "白井, 汪芳", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.jUcVjCkV.html"}, {"subitem_link_text": "英, 謙二", "subitem_link_url": "http://soar-rd.shinshu-u.ac.jp/profile/ja.WCyNjekV.html"}]}, "item_11_publisher_4": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "信州大学繊維学部"}]}, "item_11_select_64": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_11_source_id_40": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA1200368X", "subitem_source_identifier_type": "NCID"}]}, "item_11_text_66": {"attribute_name": "sortkey", "attribute_value_mlt": [{"subitem_text_value": "004"}]}, "item_1627890728808": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "鈴木,  正浩"}], "nameIdentifiers": [{"nameIdentifier": "43889", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "白井,  汪芳"}], "nameIdentifiers": [{"nameIdentifier": "43890", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "英,  謙二"}], "nameIdentifiers": [{"nameIdentifier": "43891", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2015-09-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "AFSTT10-104.pdf", "filesize": [{"value": "906.0 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 906000.0, "url": {"label": "AFSTT10-104.pdf", "url": "https://soar-ir.repo.nii.ac.jp/record/14566/files/AFSTT10-104.pdf"}, "version_id": "a366bafe-8456-4033-9799-1c297b9348f4"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "research report", "resourceuri": "http://purl.org/coar/resource_type/c_18ws"}]}, "item_title": "15-1-4 :自己集合能を持つRu(II)錯体とビオログンを含むナノファイバーの創製", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "15-1-4 :自己集合能を持つRu(II)錯体とビオログンを含むナノファイバーの創製", "subitem_title_language": "ja"}]}, "item_type_id": "11", "owner": "1", "path": ["1462"], "permalink_uri": "http://hdl.handle.net/10091/13543", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2012-02-23"}, "publish_date": "2012-02-23", "publish_status": "0", "recid": "14566", "relation": {}, "relation_version_is_last": true, "title": ["15-1-4 :自己集合能を持つRu(II)錯体とビオログンを含むナノファイバーの創製"], "weko_shared_id": -1}