{"created":"2021-03-01T06:17:31.291105+00:00","id":14566,"links":{},"metadata":{"_buckets":{"deposit":"91347907-cedb-4f17-94f1-b3e6735fd6a7"},"_deposit":{"id":"14566","owners":[],"pid":{"revision_id":0,"type":"depid","value":"14566"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00014566","sets":["1309:1314:1458:1462"]},"author_link":["43889","43890","43891"],"item_11_alternative_title_1":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"有機ナノファーバーの形成と応用"}]},"item_11_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2004-03-31","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"30","bibliographicPageStart":"29","bibliographicVolumeNumber":"10","bibliographic_titles":[{"bibliographic_title":"先進ファイバー工学研究教育拠点研究成果報告書"}]}]},"item_11_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We have synthesized new Ru(II) complexes and viologen derivatives and studied the self-assembling and gelation properties in various organic solvents. These compounds possess a L-lysine derivative as a self-organizing segment. Viologen 1 and 2 formed gels in aromatic solvents (benzene, toluene, nitrobenzene, chlorobenzene), while they precipitated in alcohols. In DMF, DMSO, and chloroform, both viologens have a high solubility and give an isotropic solution. TEM images of samples prepared from these solvents demonstrated that the viologens formed nanometer-scaled assemblies in aromatic solvents and alcohols, but not in chloroform. In toluene, 1 and 2 had a nanofiber with ca. 250- 700 nm width and nanoribbon with ca. 300- 400 nm width, formed by entangling of fine fibers (ca. 30 -IOO nm width) or ribbons (ca. 70-200 nm width). It is noteworthy that the viologens created different nanostructures; a fibrous structure for 1 and a ribbon structure for 2. On the other hand, Ru2 has a gelation ability for some aromatic solvents, but Ru1 gave isotropic solutions for these solvents. The minimum gelation concentration of Ru2 is 2 mg/ml for benzene and 4 mg/ml for toluene. The TEM images of Ru1 and Ru2 prepared from toluene showed that Ru1 and Ru2 formed a nanofiber structure. Ru2 created the network by entanglement of fine fibers , and such a hierarchical network structure is responsible for the gelation behavior of Ru2. In contrast, Ru1 forms a helical structure.","subitem_description_type":"Abstract"}]},"item_11_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_11_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"先進ファイバー工学研究教育拠点研究成果報告書 10: 29-30(2004)","subitem_description_type":"Other"}]},"item_11_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"鈴木, 正浩","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.WVnmjFkV.html"},{"subitem_link_text":"白井, 汪芳","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.jUcVjCkV.html"},{"subitem_link_text":"英, 謙二","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.WCyNjekV.html"}]},"item_11_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"信州大学繊維学部"}]},"item_11_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA1200368X","subitem_source_identifier_type":"NCID"}]},"item_1627890728808":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"鈴木,  正浩"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"白井,  汪芳"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"英,  謙二"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2015-09-28"}],"displaytype":"detail","filename":"AFSTT10-104.pdf","filesize":[{"value":"906.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"AFSTT10-104.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/14566/files/AFSTT10-104.pdf"},"version_id":"a366bafe-8456-4033-9799-1c297b9348f4"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"15-1-4 :自己集合能を持つRu(II)錯体とビオログンを含むナノファイバーの創製","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"15-1-4 :自己集合能を持つRu(II)錯体とビオログンを含むナノファイバーの創製","subitem_title_language":"ja"}]},"item_type_id":"11","owner":"1","path":["1462"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2012-02-23"},"publish_date":"2012-02-23","publish_status":"0","recid":"14566","relation_version_is_last":true,"title":["15-1-4 :自己集合能を持つRu(II)錯体とビオログンを含むナノファイバーの創製"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:05:11.066888+00:00"}