@techreport{oai:soar-ir.repo.nii.ac.jp:00014574, author = {太田, 和親 and 松瀬, 丈浩}, month = {Mar}, note = {So far as we know, metal-free phthalocyanine (PcH2) derivatives have never been synthesized by microwave heating. Recently, we have succeeded in synthesis of the metal-free derivative ((C8S)8PcH2: 3) in high yield (71%) for 10 min irradiation of microwave, by using glycerin as the reaction solvent. Furthermore, the corresponding copper (II) complex ((C8S)8PcH2: 4) could be also synthesized in 64% yield for 10 min. In comparison with the conventional solvent-free syntheses, it was much easier to separate and purify these Pc derivatives from the resulted crude products., Article, 先進ファイバー工学研究教育拠点研究成果報告書 10: 40-41(2004)}, title = {15-1-13 :マイクロ波加熱によるナノスペース機能物質の高速合成とその物性}, year = {2004} }