{"created":"2021-03-01T06:17:33.933963+00:00","id":14610,"links":{},"metadata":{"_buckets":{"deposit":"0ce670d0-bdd9-499f-88f9-77979c7410fa"},"_deposit":{"id":"14610","owners":[],"pid":{"revision_id":0,"type":"depid","value":"14610"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00014610","sets":["1309:1314:1458:1462"]},"author_link":["43986"],"item_11_alternative_title_1":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"高次機能創出加工"}]},"item_11_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2004-03-31","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"88","bibliographicPageStart":"88","bibliographicVolumeNumber":"10","bibliographic_titles":[{"bibliographic_title":"先進ファイバー工学研究教育拠点研究成果報告書"}]}]},"item_11_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"It is well-known that intramolerular hydrogen abstraction of excited carbonyl compounds via six-membered cyclic transition states (y-hydrogen abstraction) is much faster than intermolecular hydrogen abstraction. However, N,N-Dialkyl-imidazolidinetriones underwent intermolecular hydrogen abstraction on irradiation in cyclohexane in spite of the fact that they prossess y-hydrogens. This finding indicates that the intermolecular hydrogen abstraction is extremely fast. The Stem-Volmer plot for the photoreaction in cyclohexane indicated that the rate constant was 3.1 x 108 lmor-1s-1. This value is the largest among those reported for intermolecular hydrogen abstraction by excited carbonyl compound.","subitem_description_type":"Abstract"}]},"item_11_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_11_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"先進ファイバー工学研究教育拠点研究成果報告書 10: 88-88(2004)","subitem_description_type":"Other"}]},"item_11_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"信州大学繊維学部"}]},"item_11_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA1200368X","subitem_source_identifier_type":"NCID"}]},"item_1627890728808":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"青山,  弘"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2015-09-28"}],"displaytype":"detail","filename":"AFSTT10-319.pdf","filesize":[{"value":"441.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"AFSTT10-319.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/14610/files/AFSTT10-319.pdf"},"version_id":"83063ab1-976e-4d90-a038-2fc90857438f"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"15-3-19 :光反応性高分子化合物に関する基礎的研究","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"15-3-19 :光反応性高分子化合物に関する基礎的研究","subitem_title_language":"ja"}]},"item_type_id":"11","owner":"1","path":["1462"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2012-02-23"},"publish_date":"2012-02-23","publish_status":"0","recid":"14610","relation_version_is_last":true,"title":["15-3-19 :光反応性高分子化合物に関する基礎的研究"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:05:12.173510+00:00"}