@article{oai:soar-ir.repo.nii.ac.jp:00017839,
 author = {Sakai,  Toshio and Ishihara,  Akihiro and Alexandridis,  Paschalis},
 journal = {COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS},
 month = {Dec},
 note = {We report here on the silver (Ag) nanoparticle synthesis in aqueous solutions of poly(ethylene oxide)poly(propylene oxide) (PEO-PPO) block copolymers in the absence of any additional agents. In particular, we examined the effect of reaction temperature, molecular weight of PEO-PPO block copolymer and PEO-PPO block copolymer concentration on the reduction of silver ions (Ag+) and the resulting formation of Ag nanoparticles in aqueous PEO-PPO block copolymer solutions. We found that Ag nanoparticles were formed from aqueous silver nitrate (AgNO3) solutions containing PEO-PPO block copolymer above 100 degrees C. This is most likely due to the dehydration of Ag+ caused by thermal motion of water molecules in higher-temperature aqueous solution at high vapor pressure. We also found that the formation of Ag nanoparticles in aqueous PEO-PPO block copolymer solutions was enhanced with larger molecular weight of PEO-PPO block copolymer and with increase in the concentration of PEO-PPO block copolymer in aqueous solutions. (C) 2015 Elsevier B.V. All rights reserved., Article, COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS. 487:84-91 (2015)},
 pages = {84--91},
 title = {Block copolymer-mediated synthesis of silver nanoparticles from silver ions in aqueous media},
 volume = {487},
 year = {2015}
}