{"created":"2021-03-01T06:20:53.751056+00:00","id":17839,"links":{},"metadata":{"_buckets":{"deposit":"6e8b3654-c183-4097-bb9a-ea8f03f20872"},"_deposit":{"id":"17839","owners":[],"pid":{"revision_id":0,"type":"depid","value":"17839"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00017839","sets":["1221:1222"]},"author_link":["49826","49827","49828"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-12-15","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"91","bibliographicPageStart":"84","bibliographicVolumeNumber":"487","bibliographic_titles":[{"bibliographic_title":"COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We report here on the silver (Ag) nanoparticle synthesis in aqueous solutions of poly(ethylene oxide)poly(propylene oxide) (PEO-PPO) block copolymers in the absence of any additional agents. In particular, we examined the effect of reaction temperature, molecular weight of PEO-PPO block copolymer and PEO-PPO block copolymer concentration on the reduction of silver ions (Ag+) and the resulting formation of Ag nanoparticles in aqueous PEO-PPO block copolymer solutions. We found that Ag nanoparticles were formed from aqueous silver nitrate (AgNO3) solutions containing PEO-PPO block copolymer above 100 degrees C. This is most likely due to the dehydration of Ag+ caused by thermal motion of water molecules in higher-temperature aqueous solution at high vapor pressure. We also found that the formation of Ag nanoparticles in aqueous PEO-PPO block copolymer solutions was enhanced with larger molecular weight of PEO-PPO block copolymer and with increase in the concentration of PEO-PPO block copolymer in aqueous solutions. (C) 2015 Elsevier B.V. All rights reserved.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ(コンテンツの種類)","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS. 487:84-91 (2015)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Sakai, Toshio","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.OhkpjFkV.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_text":"Web of Science","subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000365360000011"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ELSEVIER SCIENCE BV"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1016/j.colsurfa.2015.09.058"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.colsurfa.2015.09.058","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ "}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0927-7757","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA10892561","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Sakai, Toshio"}],"nameIdentifiers":[{"nameIdentifier":"49826","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ishihara, Akihiro"}],"nameIdentifiers":[{"nameIdentifier":"49827","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Alexandridis, Paschalis"}],"nameIdentifiers":[{"nameIdentifier":"49828","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-12-15"}],"displaytype":"detail","filename":"Block_copolymer-mediated_synthesis_silver_nanoparticles.pdf","filesize":[{"value":"1.1 MB"}],"format":"application/pdf","licensefree":"© 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Block_copolymer-mediated_synthesis_silver_nanoparticles.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/17839/files/Block_copolymer-mediated_synthesis_silver_nanoparticles.pdf"},"version_id":"af2a2382-5114-4f4f-9e2b-7b3da1096a83"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Silver nanopartide","subitem_subject_scheme":"Other"},{"subitem_subject":"Poly(ethylene oxide)-poly(propylene oxide) block copolymer","subitem_subject_scheme":"Other"},{"subitem_subject":"Silver nitrate","subitem_subject_scheme":"Other"},{"subitem_subject":"Silver ion reduction","subitem_subject_scheme":"Other"},{"subitem_subject":"Reaction temperature","subitem_subject_scheme":"Other"},{"subitem_subject":"Hydration","subitem_subject_scheme":"Other"},{"subitem_subject":"Dehydration","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Block copolymer-mediated synthesis of silver nanoparticles from silver ions in aqueous media","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Block copolymer-mediated synthesis of silver nanoparticles from silver ions in aqueous media","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1222"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2016-02-03"},"publish_date":"2016-02-03","publish_status":"0","recid":"17839","relation_version_is_last":true,"title":["Block copolymer-mediated synthesis of silver nanoparticles from silver ions in aqueous media"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:12:28.474476+00:00"}