{"created":"2021-03-01T06:20:54.246003+00:00","id":17847,"links":{},"metadata":{"_buckets":{"deposit":"e11b0557-7946-4afc-8820-5539a66df7e1"},"_deposit":{"id":"17847","owners":[],"pid":{"revision_id":0,"type":"depid","value":"17847"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00017847","sets":["1626:1627"]},"author_link":["49882","49883","49884","49885","49886","49887","49888","49889","49890"],"control_number":"17847","item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-11","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"523","bibliographicPageStart":"518","bibliographicVolumeNumber":"94","bibliographic_titles":[{"bibliographic_title":"CARBON"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We report a bimetallic Zn/Al complex as an efficient inorganic dispersant for SWCNT, synthesized from Zn(CH3COO)(2) and Al(NO3)(3). The Zn/Al complex shows more than four times greater efficiency at dispersing SWCNT than widely used surfactants (CTAB and SDS). Besides remarkable dispersibility, the Zn/Al complex does not foam upon any shaking treatment and it can be used just after quick dissolution of the powdered form, which is a marked advantage over surfactants. The Zn/Al complex, containing amorphous Al(CH3COO)(3) and a complex of Zn2+ and NO3- ions, should have a unique dispersion mechanism, differing from the surfactants. Al(CH3COO)(3) has higher affinity for SWCNT than ions, adsorbing onto its surface in the first layer and attracting Zn2+ and NO3- ions. Charge transfer interactions between the Zn/Al complex and SWCNT, as evidenced by optical absorption spectroscopy, should induce a charge on SWCNT; the zeta potential of such coated SWCNT was +55 mV, indicating a high dispersion stability in aqueous media. Hence, the Zn/Al complex can widen the applications of SWCNT to various technologies such as the transparent and conductive films, as well as high performance composite polymers. (C) 2015 Elsevier Ltd. All rights reserved.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"CARBON. 94:518-523 (2015)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Hayashi, Takuya","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.jmLUbpkh.html"},{"subitem_link_text":"Hattori, Yoshiyuki","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.jmyejFkV.html"},{"subitem_link_text":"Kaneko, Katsumi","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.HafNZVyC.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000360294900063"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"PERGAMON-ELSEVIER SCIENCE LTD"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1016/j.carbon.2015.07.025"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.carbon.2015.07.025","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/"}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0008-6223","subitem_source_identifier_type":"PISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00598943","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kukobat,  Radovan","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Minami,  Daiki","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hayashi,  Takuya","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hattori,  Yoshiyuki","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Matsuda,  Takafumi","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sunaga,  Motoo","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Bharti,  Bhuvnesh","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Asakura,  Kiyotaka","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kaneko,  Katsumi","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-11-01"}],"displaytype":"detail","filename":"Sol-gel_chemistry_mediated_ZnAl-based_complex.pdf","filesize":[{"value":"840.5 kB"}],"format":"application/pdf","licensefree":"© 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Sol-gel_chemistry_mediated_ZnAl-based_complex.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/17847/files/Sol-gel_chemistry_mediated_ZnAl-based_complex.pdf"},"version_id":"85e42827-ec81-4eaf-b229-e642641aa1aa"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Sol-gel chemistry mediated Zn/Al-based complex dispersant for SWCNT in water without foam formation","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Sol-gel chemistry mediated Zn/Al-based complex dispersant for SWCNT in water without foam formation","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1627"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2016-02-03"},"publish_date":"2016-02-03","publish_status":"0","recid":"17847","relation_version_is_last":true,"title":["Sol-gel chemistry mediated Zn/Al-based complex dispersant for SWCNT in water without foam formation"],"weko_creator_id":"1","weko_shared_id":3},"updated":"2022-12-14T04:12:30.685356+00:00"}