{"created":"2021-03-01T06:20:54.860797+00:00","id":17862,"links":{},"metadata":{"_buckets":{"deposit":"bbad43e2-06f8-4369-bd21-af424ac06626"},"_deposit":{"id":"17862","owners":[],"pid":{"revision_id":0,"type":"depid","value":"17862"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00017862","sets":["1162:1163"]},"author_link":["49940","49941","49942"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-02-11","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6","bibliographicPageEnd":"981","bibliographicPageStart":"977","bibliographicVolumeNumber":"71","bibliographic_titles":[{"bibliographic_title":"TETRAHEDRON"}]}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The reaction of chiral imines, derived from aromatic aldehydes and (S)-valinol, with a Grignard reagent in the presence of Mg(0) afforded imino-pinacol coupling products instead of alkylated amines, with a high level of diastereoselectivity. The chiral auxiliary in the product was successfully removed via dehydration followed by hydrolysis, and the corresponding (R,R)-ethylenediamine derivative was obtained as the N-Boc protected form. (C) 2014 Elsevier Ltd. All rights reserved.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"TETRAHEDRON. 71(6):977-981 (2015)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Fujimoto, Tetsuya","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.jVAmjekV.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000348950300009"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"PERGAMON-ELSEVIER SCIENCE LTD"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1016/j.tet.2014.12.034"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.tet.2014.12.034","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ "}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0040-4020","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00861787","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kitajima,  Kai"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nagatomo,  Ryota"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fujimoto,  Tetsuya"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-02-11"}],"displaytype":"detail","filename":"Diastereoselective_imino-pinacol_coupling_chiral_imines.pdf","filesize":[{"value":"2.6 MB"}],"format":"application/pdf","licensefree":"© 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Diastereoselective_imino-pinacol_coupling_chiral_imines.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/17862/files/Diastereoselective_imino-pinacol_coupling_chiral_imines.pdf"},"version_id":"38cda42d-596d-497d-9368-8cda42d9407b"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Imino-pinacol coupling","subitem_subject_scheme":"Other"},{"subitem_subject":"Chiral 1,2-diamine","subitem_subject_scheme":"Other"},{"subitem_subject":"Grignard reagent","subitem_subject_scheme":"Other"},{"subitem_subject":"Magnesium","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Diastereoselective imino-pinacol coupling of chiral imines promoted by Mg(0) and a Grignard reagent","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Diastereoselective imino-pinacol coupling of chiral imines promoted by Mg(0) and a Grignard reagent","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1163"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2016-02-04"},"publish_date":"2016-02-04","publish_status":"0","recid":"17862","relation_version_is_last":true,"title":["Diastereoselective imino-pinacol coupling of chiral imines promoted by Mg(0) and a Grignard reagent"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:12:29.770183+00:00"}