{"created":"2021-03-01T06:20:58.256473+00:00","id":17918,"links":{},"metadata":{"_buckets":{"deposit":"1ed1bc84-607c-435c-beef-dab7806b9e6a"},"_deposit":{"id":"17918","owners":[],"pid":{"revision_id":0,"type":"depid","value":"17918"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00017918","sets":["1309:1310"]},"author_link":["50031","50032","50033"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"14","bibliographicPageEnd":"1539","bibliographicPageStart":"1534","bibliographicVolumeNumber":"216","bibliographic_titles":[{"bibliographic_title":"MACROMOLECULAR CHEMISTRY AND PHYSICS"}]}]},"item_6_description_19":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Article first published online: 11 JUN 2015","subitem_description_type":"Other"}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Anionic polymerization of n-butyl acrylate (nBA) in toluene initiated with a binary initiator, isopropyl α-lithioisobutyrate/ethylaluminum bis(2,6-di-tert-butylphenoxide) at −60 °C, is terminated with ethyl α-(chloromethyl)acrylate (ECMA) to afford a poly(nBA) possessing an acryloyl group at the terminal with 80% of termination efficiency. The reactivity of nBA against a polymer anion of methyl methacrylate formed under identical conditions is estimated relative to the termination with ECMA by reacting a mixture of nBA and ECMA followed by 1H NMR spectroscopic chain-end analysis; the relative reactivity of nBA is found 80 times or more higher than ECMA.","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"MACROMOLECULAR CHEMISTRY AND PHYSICS. 216(14):1534-1539 (2015)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Kohsaka, Yasuhiro","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.WNTUPVca.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000358120700005"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"WILEY-V C H VERLAG GMBH"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1002/macp.201500100"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/macp.201500100","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: MACROMOLECULAR CHEMISTRY AND PHYSICS. 216(14):1534-1539 (2015), which has been published in final form at https://doi.org/10.1002/macp.201500100 This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1022-1352","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA10984295","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kohsaka,  Yasuhiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ishihara,  Shoya"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kitayama,  Tatsuki"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-06-11"}],"displaytype":"detail","filename":"Termination_of_Living_Anionic_Polymerization.pdf","filesize":[{"value":"217.9 kB"}],"format":"application/pdf","licensefree":"This is the peer reviewed version of the following article: MACROMOLECULAR CHEMISTRY AND PHYSICS. 216(14):1534-1539 (2015), which has been published in final form at https://doi.org/10.1002/macp.201500100 This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Termination_of_Living_Anionic_Polymerization.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/17918/files/Termination_of_Living_Anionic_Polymerization.pdf"},"version_id":"5f5558af-dcf4-42cf-ad4a-b6497a1c7678"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"alpha-substituted acrylate","subitem_subject_scheme":"Other"},{"subitem_subject":"anionic polymerization","subitem_subject_scheme":"Other"},{"subitem_subject":"end-functional polymer","subitem_subject_scheme":"Other"},{"subitem_subject":"relative reactivity","subitem_subject_scheme":"Other"},{"subitem_subject":"terminator","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Termination of Living Anionic Polymerization of Butyl Acrylate with alpha-(Chloromethyl) acrylate for End-Functionalization and Application to the Evaluation of Monomer Reactivity","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Termination of Living Anionic Polymerization of Butyl Acrylate with alpha-(Chloromethyl) acrylate for End-Functionalization and Application to the Evaluation of Monomer Reactivity","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1310"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2016-03-23"},"publish_date":"2016-03-23","publish_status":"0","recid":"17918","relation_version_is_last":true,"title":["Termination of Living Anionic Polymerization of Butyl Acrylate with alpha-(Chloromethyl) acrylate for End-Functionalization and Application to the Evaluation of Monomer Reactivity"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:27:26.648839+00:00"}