{"created":"2021-03-01T06:20:58.317541+00:00","id":17919,"links":{},"metadata":{"_buckets":{"deposit":"ec176968-2db8-4699-a1e7-ea1624cf2161"},"_deposit":{"id":"17919","owners":[],"pid":{"revision_id":0,"type":"depid","value":"17919"},"status":"published"},"_oai":{"id":"oai:soar-ir.repo.nii.ac.jp:00017919","sets":["1309:1310"]},"author_link":["50034","50035","50036","50037","50038"],"item_1628147817048":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_6_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-04-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"7","bibliographicPageEnd":"961","bibliographicPageStart":"955","bibliographicVolumeNumber":"54","bibliographic_titles":[{"bibliographic_title":"Journal of Polymer Science Part A: Polymer Chemistry"}]}]},"item_6_description_19":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"First published: 16 October 2015","subitem_description_type":"Other"}]},"item_6_description_20":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"2,6-Dimethyl-5-methylene-1,3-dioxa-4-one (DMDO), a cyclic acrylate possessing acetal–ester linkage, was obtained as a mixture of cis- and trans-isomers (95:5) from Baylis–Hillman reaction of an aryl acrylate. The radical and anionic polymerizations of DMDO yielded the corresponding vinyl polymers without any side reactions such as cleavage of the acetal–ester linkage. The polymerization behaviors were significantly different from that of the acyclic acrylate, α-(hydroxymethyl)acrylic acid, which was expected inactive against polymerization due to the steric hindrance around the vinylidene group by the α-substituent. The acetal–ester linkage of the obtained polymer (P1) was completely cleaved via acid hydrolysis to afford a water soluble polymer, P2. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016, 54, 955–961","subitem_description_type":"Abstract"}]},"item_6_description_30":{"attribute_name":"資源タイプ（コンテンツの種類）","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_type":"Other"}]},"item_6_description_5":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"Journal of Polymer Science Part A: Polymer Chemistry. 54(7):955-961 (2016)","subitem_description_type":"Other"}]},"item_6_link_3":{"attribute_name":"信州大学研究者総覧へのリンク","attribute_value_mlt":[{"subitem_link_text":"Kohsaka, Yasuhiro","subitem_link_url":"http://soar-rd.shinshu-u.ac.jp/profile/ja.WNTUPVca.html"}]},"item_6_link_67":{"attribute_name":"WoS","attribute_value_mlt":[{"subitem_link_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=ShinshuUniv&SrcApp=ShinshuUniv&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000371610100009"}]},"item_6_publisher_4":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"WILEY"}]},"item_6_relation_48":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"10.1002/pola.27931"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/pola.27931","subitem_relation_type_select":"DOI"}}]},"item_6_rights_62":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: Journal of Polymer Science Part A: Polymer Chemistry. 54(7):955-961 (2016), which has been published in final form at https://doi.org/10.1002/pola.27931 This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."}]},"item_6_source_id_35":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0887-624X","subitem_source_identifier_type":"ISSN"}]},"item_6_source_id_40":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA1068915X","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kohsaka,  Yasuhiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Matsumoto,  Yusuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Zhang,  Tianyi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Matsuhashi,  Yosuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kitayama,  Tatsuki"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-10-16"}],"displaytype":"detail","filename":"alpha-exomethylene_lactone_possessing_acetal–ester_linkage.pdf","filesize":[{"value":"528.9 kB"}],"format":"application/pdf","licensefree":"This is the peer reviewed version of the following article: Journal of Polymer Science Part A: Polymer Chemistry. 54(7):955-961 (2016), which has been published in final form at https://doi.org/10.1002/pola.27931 This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"alpha-exomethylene_lactone_possessing_acetal–ester_linkage.pdf","url":"https://soar-ir.repo.nii.ac.jp/record/17919/files/alpha-exomethylene_lactone_possessing_acetal–ester_linkage.pdf"},"version_id":"41223aa5-aa16-4bd2-b65b-dec7aaeb7b3e"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"α-exomethylene lactone possessing acetal–ester linkage: Polymerization and postpolymerization modification for water-soluble polymer","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"α-exomethylene lactone possessing acetal–ester linkage: Polymerization and postpolymerization modification for water-soluble polymer","subitem_title_language":"en"}]},"item_type_id":"6","owner":"1","path":["1310"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2016-03-23"},"publish_date":"2016-03-23","publish_status":"0","recid":"17919","relation_version_is_last":true,"title":["α-exomethylene lactone possessing acetal–ester linkage: Polymerization and postpolymerization modification for water-soluble polymer"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-14T04:27:26.854253+00:00"}